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线性分子式:
[(CH3)3Si]2NNa
化学文摘社编号:
分子量:
183.37
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-983-8
Beilstein/REAXYS Number:
3629917
MDL number:
产品名称
双(三甲基硅基)氨基钠, 95%
InChI key
WRIKHQLVHPKCJU-UHFFFAOYSA-N
InChI
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
SMILES string
C[Si](C)(C)N([Na])[Si](C)(C)C
assay
95%
form
powder or chunks
bp
202 °C/at 1-3 hPa
mp
171-175 °C (lit.)
175-171 °C (lit.)
Quality Level
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Application
用于卡宾的生成、亚磺酰胺的胺化以及镧系元素配合物的制备。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Journal of the Chemical Society. Perkin Transactions 1, 1923-1923 (1992)
Angewandte Chemie (International Edition in English), 32, 1208-1208 (1993)
Journal of the American Chemical Society, 116, 7637-7637 (1994)
Werner Mormann et al.
Macromolecular bioscience, 9(4), 369-375 (2008-11-26)
Trimethylsilylation of cellulose in different 1,3-dialkylimidazolium ionic liquids (IL) with hexamethyldisilazane (HMDS) as a silylating agent was investigated. Trimethylsilyl (TMSi) cellulose with a degree of substitution (DS) greater than 1 is insoluble in the IL. The maximum DS obtained depends
Haoyu Tang et al.
Biomacromolecules, 11(6), 1585-1592 (2010-05-15)
A series of poly(gamma-chloropropyl-L-glutamate) (PCPLG) with controlled polymer molecular weight (MW = 5-28 kg x mol(-1)) and molecular weight distribution (PDI = 1.16-1.26) have been prepared from hexamethyldisilazane (HMDS)-mediated ring-opening polymerization (ROP) of gamma-chloropropyl-L-glutamic acid based N-carboxylanhydride (CP-NCA). CD, FTIR
商品
Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.
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