所有图片(1)
别名:
双(三甲基硅基)丙二酸酯
线性分子式:
(CH3)3SiOCOCH2COOSi(CH3)3
CAS号:
分子量:
248.42
Beilstein:
2212115
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
检测方案
98%
折射率
n20/D 1.416 (lit.)
bp
63-66 °C/1 mmHg (lit.)
密度
0.974 g/mL at 25 °C (lit.)
SMILES字符串
C[Si](C)(C)OC(=O)CC(=O)O[Si](C)(C)C
InChI
1S/C9H20O4Si2/c1-14(2,3)12-8(10)7-9(11)13-15(4,5)6/h7H2,1-6H3
InChI key
ATCKJLDGNXGLAO-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
Bis(trimethylsilyl) malonate is precursor for metal-organic chemical vapor deposition (MOCVD) of HfO2 and ZrO2 thin films. It undergoes acylation reaction with acid chlorides and acyl carbonates in the presence of triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones.
应用
制备 β-酮酸和甲基酮的中间体。
Synthesis of ?-Keto Acids and Methyl Ketones Using Bis (trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides.
Rathke MW and Nowak MA.
Synthetic Communications, 15(12), 1039-1049 (1985)
Malonates in cyclocondensation reactions.
Stadlbauer W, et al.
Molecules (Basel), 6(4), 338-352 (2001)
Synthetic Communications, 15, 1039-1039 (1985)
Ramasamy Pothiraja et al.
Dalton transactions (Cambridge, England : 2003), (4)(4), 654-663 (2009-04-22)
New Hf and Zr malonate complexes have been synthesized by the reaction of metal amides with different malonate ligands (L = dimethyl malonate (Hdmml), diethyl malonate (Hdeml), di-tert-butyl malonate (Hdbml) and bis(trimethylsilyl) malonate (Hbsml)). Homoleptic eight-coordinated monomeric compounds of the
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门