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方案
97%
表单
liquid
折射率
n20/D 1.414 (lit.)
沸点
38-39 °C/13 mmHg (lit.)
密度
0.891 g/mL at 25 °C (lit.)
官能团
ester
SMILES字符串
COC(=O)C[Si](C)(C)C
InChI
1S/C6H14O2Si/c1-8-6(7)5-9(2,3)4/h5H2,1-4H3
InChI key
JIHUZDFFYVRXKP-UHFFFAOYSA-N
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一般描述
Methyl trimethylsilylacetate on reaction with lithium diisopropylamide in THF at -78°C yields methyl lithiotrimethylsilylacetate. It also undergoes Peterson olefination to yield mainly Z-isomers of steroid 17β-side chain methyl acrylates.
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
91.4 °F - closed cup
闪点(°C)
33 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Z-Isomers of Steroid 17?-Side Chain Methyl Acrylates.
Pouzar V, et al.
Collection of Czechoslovak Chemical Communications, 57(9), 1928-1936 (1992)
Conjugate addition of lithiotrimethylsilylacetate. A simple synthesis of methyl jasmonate via vicinal double alkylation.
Nishiyama H, et al.
Tetrahedron Letters, 25(23), 2487-2488 (1984)
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