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质量水平
方案
97%
反应适用性
core: titanium
reagent type: catalyst
mp
260-280 °C (dec.) (lit.)
密度
1.6 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key
XKLWATAZDMHTSH-UHFFFAOYSA-L
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应用
由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。
警示用语：
Danger
危险声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Ramón Hernández et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(1), 178-183 (2009-09-24)
Replacement of the ancillary ligand in titanocene dichloride by amino acids provides titanocene species with high water solubility. As part of our research efforts in the area of titanium-based antitumor agents, we have investigated the cytotoxic activity of Cp(2)TiCl(2) and
Maria Pavlaki et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 14(6), 947-957 (2009-04-25)
Titanocene dichloride, the most studied metallocene, exhibits antiproliferative activity in a wide spectrum of murine and human tumours. In this article it is demonstrated that titanocene dichloride inhibits tumour gelatinases in a dose-dependent manner. Substrate saturation experiments and the fact
Sumit Saha et al.
The Journal of organic chemistry, 76(17), 7229-7234 (2011-07-29)
Titanocene(III) chloride (Cp(2)TiCl) mediated radical induced allylation of aldimines for the preparation of homoallyl amines is described. The radical was generated from the allyl bromide using Cp(2)TiCl as the radical source. Formal synthesis of C(4)-C(5')-linked 4'-deoxy aza-disaccharide is demonstrated and
Samaresh Jana et al.
The Journal of organic chemistry, 70(20), 8252-8254 (2005-11-10)
[Chemical reaction: see text] A radical based Wagner-Meerwein-type rearrangement has been observed in camphoric systems. The radical was generated from the epoxide using Cp2TiCl as the radical source. The radical initiator Cp2TiCl was prepared in situ from commercially available Cp2TiCl2
[Determination of organometallic antitumor crude drug titanocene dichloride by NP-HPLC].
Yunlan Li et al.
Se pu = Chinese journal of chromatography, 25(2), 282-283 (2007-06-22)
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