234826
双(环戊二烯基)二氯化钛(IV)
97%
别名:
Cp2TiCl2, 二氯双(1,3-环戊二烯基)钛, 二氯双环戊二烯基钛, 二氯环戊二烯钛, Cp2TiCl2, 二氯二茂钛, 二氯双(环戊二烯基)钛(IV)
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关于此项目
经验公式（希尔记法）:
C10H10Cl2Ti
化学文摘社编号:
分子量:
248.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-035-9
MDL number:
InChI key
XKLWATAZDMHTSH-UHFFFAOYSA-L
InChI
1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
SMILES string
Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
assay
97%
reaction suitability
core: titanium, reagent type: catalyst
mp
260-280 °C (dec.) (lit.)
density
1.6 g/mL at 25 °C (lit.)
Quality Level
Application
由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Alberto García-Peñas et al.
Journal of inorganic biochemistry, 106(1), 100-110 (2011-11-25)
Titanocene dichloride [Ti(η(5)-C(5)H(5))(2)Cl(2)] (1), has been grafted onto dehydrated hydroxyapatite (HAP), Al(2)O(3) and two mesoporous silicas MSU-2 (Michigan State University Silica type 2) and HMS (Hexagonal Mesoporous Silica), to give the novel materials HAP/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S1) (1.01 wt.% Ti), Al(2)O(3)/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S2)
Ping Chen et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 76(3), 413-420 (2010-09-22)
In order to improve both safety and efficacy of cancer chemotherapy of titanocene dichloride and overcome the shortcomings such as instability and short half-life in the human body, we report a controlled release system of titanocene dichloride by electrospun fiber
Li Ming Gao et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 12(7), 959-967 (2007-06-15)
Functionalization of cyclopentadienyl (Cp) ligands and incorporation of these into a Ti(IV) center require careful design and selection of the appropriate synthetic routes to obtain the desired product in reasonably good yields. As part of our research efforts in the
Katherine M Buettner et al.
Dalton transactions (Cambridge, England : 2003), 40(37), 9580-9588 (2011-08-19)
Since the discovery of the anticancer activity of titanocene dichloride (TDC), many derivatives have been developed and evaluated. MKT4, a soluble, water-stable formulation of TDC, was used for both Phase I and Phase II human clinical trials. This formulation is
Mauro Ravera et al.
Journal of inorganic biochemistry, 99(12), 2264-2269 (2005-10-08)
Titanocene dichloride exhibits anti-proliferative activity in a wide spectrum of murine and human tumors. Although it is still unclear as to which species are active in biological media, they all readily deliver Ti(IV) to transferrin, the protein that transports iron
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