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Merck
CN

234664

Sigma-Aldrich

(-)-鹰爪豆碱 硫酸酯 五水合物

99%

别名:

(-)-金雀花碱 硫酸盐, 硫酸司巴丁 五水合物

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About This Item

经验公式(希尔记法):
C15H26N2 · H2SO4 · 5H2O
CAS号:
分子量:
422.54
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:

方案

99%

旋光性

[α]25/D −12.4°, c = 1 in ethanol

mp

133-140 °C (lit.)

SMILES字符串

O.O.O.O.O.OS(O)(=O)=O.C1CCN2C[C@@H]3C[C@@H](CN4CCCC[C@H]34)[C@@H]2C1

InChI

1S/C15H26N2.H2O4S.5H2O/c1-3-7-16-11-13-9-12(14(16)5-1)10-17-8-4-2-6-15(13)17;1-5(2,3)4;;;;;/h12-15H,1-11H2;(H2,1,2,3,4);5*1H2/t12-,13-,14-,15+;;;;;;/m0....../s1

InChI key

WNSDDGBLIALDPB-LIELMIIZSA-N

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Mass spectrometry of metal complexes of bis-quinolizidine alkaloids: EI and ESI mass spectral study of Co(+2), Ni(+2), Cu(+2) and Zn(+2) 2-methylsparteine complexes.
Beata Jasiewicz et al.
Journal of mass spectrometry : JMS, 47(3), 347-351 (2012-03-21)
Deyong Su et al.
The Journal of organic chemistry, 76(1), 188-194 (2010-12-03)
Total synthesis of (+)-epilupinine was accomplished in nine steps and in 48% overall yield, in which INOC was used as the key step for the construction of the quinolizidine skeleton. We found that it was an extremely difficult task to
Antonio G De Crisci et al.
Dalton transactions (Cambridge, England : 2003), 39(11), 2888-2902 (2010-03-05)
A cationic rhodium-sparteine complex, [((-)-sparteine)Rh(eta(4)-COD)](+) (1(+); COD = 1,5-cyclooctadiene) was obtained, isolated as its tetrafluoroborate salt (1BF(4)), and characterized using X-ray crystallography and multinuclear ((1)H, (13)C) NMR spectroscopy. This is the first structurally characterized sparteine complex of rhodium. The Rh-N
Yuu Shibano et al.
Chemical & pharmaceutical bulletin, 59(2), 249-253 (2011-02-08)
We studied the detection of drug-metabolizing enzyme inhibitiors using column-switching high performance liquid chromatography with tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)(3)(2+))-electrogenerated chemiluminescence detection. This can be applied to evaluate the genetic diversity concerning the ability of cytochrome P450 (CYP) 2D6 to metabolize drug in
Michael Tait et al.
Organic letters, 15(1), 34-37 (2012-12-21)
In the presence of (-)-sparteine or a (+)-sparteine surrogate, organolithiums add to N-alkenyl-N'-arylureas to give benzylic organolithiums in an enantioselective manner. Under the influence of DMPU, these organolithiums undergo rearrangement with migration of the N'-aryl ring from N to C

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