所有图片(1)
别名:
苯磺酰基乙酸甲酯
线性分子式:
C6H5SO2CH2COOCH3
CAS号:
分子量:
214.24
Beilstein:
2051463
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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检测方案
97%
折射率
n20/D 1.535 (lit.)
bp
165 °C/0.05 mmHg (lit.)
密度
1.305 g/mL at 20 °C (lit.)
SMILES字符串
COC(=O)CS(=O)(=O)c1ccccc1
InChI
1S/C9H10O4S/c1-13-9(10)7-14(11,12)8-5-3-2-4-6-8/h2-6H,7H2,1H3
InChI key
NLEAIFBNKPYTGN-UHFFFAOYSA-N
基因信息
human ... LOC129293(129293)
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应用
Methyl phenylsulfonylacetate has been used:
- in a key step during the synthesis of (−)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida
- in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium
- in three step synthesis of 2-(hydroxymethyl)indene
WGK
WGK 3
闪点(°F)
172.4 °F
闪点(°C)
78 °C
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
An improved synthesis of 2-(hydroxymethyl) indene.
Palandoken H, et al.
Organic Prep. and Proc. Int., 28(6), 702-704 (1996)
Methyl Carboxymethylenation of Alcohols via Dehydrative Alkylation.
YuJ, et al.
Synlett, 1995(11), 1127-1128 (1995)
Koichiro Ota et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(42), 13531-13537 (2012-09-12)
(-)-Hybridalactone (1) is a marine eicosanoid isolated from the red alga Laurencia hybrida. This natural product contains cyclopropane, cyclopentane, 13-membered macrolactone and epoxide ring systems incorporating seven stereogenic centers. Moreover, this compound has an acid-labile skipped Z,Z-diene motif. In this
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