推荐产品
质量水平
方案
97%
表单
liquid
折射率
n20/D 1.401 (lit.)
沸点
44-45.5 °C/9 mmHg (lit.)
密度
1.007 g/mL at 25 °C (lit.)
官能团
ester
ether
SMILES字符串
CCOC(=O)COC
InChI
1S/C5H10O3/c1-3-8-5(6)4-7-2/h3-4H2,1-2H3
InChI key
JLEKJZUYWFJPMB-UHFFFAOYSA-N
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应用
Ethyl methoxyacetate was used:
- as acyl donor during the preparation of enantiomers of several phenylethylamines
- as acylation reagent for the aminolysis of 1-phenylethanamine
- in an industrial, lipase-catalysed kinetic resolution of primary amine
Lourdes Muñoz et al.
Organic & biomolecular chemistry, 9(23), 8171-8177 (2011-10-06)
Both enantiomers of several phenylethylamines, structurally related to amphetamine, have been prepared in good yields and excellent enantiomeric purity by enzymatic kinetic resolution using CAL-B and ethyl methoxyacetate as the acyl donor. In the case of the 4-hydroxyderivative of amphetamine
Ulf Hanefeld
Organic & biomolecular chemistry, 1(14), 2405-2415 (2003-09-06)
Commonly, hydrolase-catalysed reactions are used for kinetic resolutions of alcohols, amines and acids. Only a few applications in total syntheses have been described. Most of these examples are for the synthesis of amides and peptides. Here, the synthesis of all
Saija Sirén et al.
Molecules (Basel, Switzerland), 25(4) (2020-02-23)
The enantiomers of aromatic 4-dibenzocyclooctynol (DIBO), used for radiolabeling and subsequent conjugation of biomolecules to form radioligands for positron emission tomography (PET), were separated by kinetic resolution using lipase A from Candida antarctica (CAL-A). In optimized conditions, (R)-DIBO [(R)-1, ee
C Saito et al.
Biotechnic & histochemistry : official publication of the Biological Stain Commission, 74(1), 40-48 (1999-04-06)
An in situ hybridization procedure resulting in both high resolution and sensitivity was established by using the removable methyl methacrylate resin, Technovit 9100. Young bicellular pollen of tobacco (Nicotiana tabacum L. SR-1) was embedded in Technovit 9100 resin and sectioned.
T S Shih et al.
Archives of environmental health, 56(1), 20-25 (2001-03-21)
Urinary 2-methoxy acetic acid reportedly has a long half-life (77.1 hr) in humans. The authors studied urinary 2-methoxy acetic acid in a group of 18 workers exposed to 2-methoxy ethanol from Monday to Saturday following a 7-d cease in production.
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