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经验公式(希尔记法):
C10H16
化学文摘社编号:
分子量:
136.23
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-792-4
Beilstein/REAXYS Number:
2038651
MDL number:
产品名称
(+)-2-蒈烯, 97%
InChI key
IBVJWOMJGCHRRW-BDAKNGLRSA-N
InChI
1S/C10H16/c1-7-4-5-8-9(6-7)10(8,2)3/h6,8-9H,4-5H2,1-3H3/t8-,9+/m1/s1
SMILES string
CC1=C[C@H]2[C@@H](CC1)C2(C)C
assay
97%
optical activity
[α]20/D +90.0°, c = 6 in ethanol
refractive index
n20/D 1.476 (lit.)
bp
167-168 °C (lit.)
density
0.862 g/mL at 25 °C (lit.)
Quality Level
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Application
(+)-2-蒈烯可作为手性合成砌块合成手性非外消旋2,2-二甲基-1,3-二取代环丙烷衍生物。也可用作(+)-α-榄香烯的对映选择性合成试剂。
General description
(+)-2-蒈烯是一种天然的双环单萜烯,常见于各种植物,包括迷迭香、杉树和松树。在有机合成中主要用作各种手性化合物的手性合成砌块。
Codruta Ignea et al.
Nature communications, 10(1), 3799-3799 (2019-08-25)
Synthetic biology efforts for the production of valuable chemicals are frequently hindered by the structure and regulation of the native metabolic pathways of the chassis. This is particularly evident in the case of monoterpenoid production in Saccharomyces cerevisiae, where the
Haocheng Liu et al.
Foods (Basel, Switzerland), 9(1) (2020-01-16)
Mangoes (Mangifera indica L.) are wildly cultivated in China with different commercial varieties; however, characterization of their aromatic profiles is limited. To better understand the aromatic compounds in different mango fruits, the characteristic aromatic components of five Chinese mango varieties
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