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Merck
CN

232025

Sigma-Aldrich

4-(三氟甲基)苄醇

98%

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About This Item

线性分子式:
CF3C6H4CH2OH
CAS号:
分子量:
176.14
Beilstein:
1450174
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

方案

98%

折射率

n20/D 1.459 (lit.)

沸点

78-80 °C/4 mmHg (lit.)

密度

1.286 g/mL at 25 °C (lit.)

SMILES字符串

OCc1ccc(cc1)C(F)(F)F

InChI

1S/C8H7F3O/c9-8(10,11)7-3-1-6(5-12)2-4-7/h1-4,12H,5H2

InChI key

MOOUWXDQAUXZRG-UHFFFAOYSA-N

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一般描述

Photocatalytic oxidation of 4-(trifluoromethyl)benzyl alcohol to corresponding aldehydes on TiO2 photocatalyst under O2 atmosphere has been reported.

应用

用于(例如)磷酰甲酸酯药物前体和水合铬(IV)的动力学研究的试剂。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

213.8 °F - closed cup

闪点(°C)

101 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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Journal of the American Chemical Society, 114, 4205-4205 (1992)
Selective photocatalytic oxidation of benzyl alcohol and its derivatives into corresponding aldehydes by molecular oxygen on titanium dioxide under visible light irradiation.
Higashimoto S, et al.
J. Catal., 266(2), 279-285 (2009)
J. Chem. Soc. Perkin Trans. II, 1145-1145 (1992)
One-pot synthesis of fluorine-containing alkenes from in situ-generated stabilized phosphorus ylides.
Pakravan P, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 182(3), 545-549 (2007)
D C Anderson et al.
Biochemistry, 19(24), 5486-5493 (1980-11-25)
The interactions of horse liver alcohol dehydrogenase (LADH) with the rho-trifluoromethyl derivatives of benzyl alcohol, benzaldehyde, and benzoic acid have been investigated by use of 19F nuclear magnetic resonance. The aldehyde and alcohol are good substrates for the enzyme and

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