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About This Item
线性分子式:
CuBr · CH3SCH3
CAS号:
分子量:
205.58
Beilstein:
4386581
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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应用
用于格氏试剂（烷基、烯基、芳基）加成为富勒烯的催化剂。该反应对 [60]富勒烯添加 5 个有机基团，对 [70]富勒烯添加 3 个基团。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Rossiter, B. E. et al.B. E.; Swingle, N. M.
Chemical Reviews, 92, 771-771 (1992)
Organic Syntheses, 83, 80-80 (2006)
Beatriz Pacheco Berciano et al.
Organic letters, 12(18), 4038-4041 (2010-08-26)
The copper-catalyzed direct alkynylation of azoles with 1,1-dibromo-1-alkenes as electrophiles is described. These easily accessible substrates are a useful addition to the field of direct alkynylations in an efficient and functional group tolerant reaction to provide a straightforward entry to
Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent.
Tobias Robert et al.
Angewandte Chemie (International ed. in English), 47(40), 7718-7721 (2008-09-06)
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