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质量水平
方案
98%
表单
liquid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
折射率
n20/D 1.609 (lit.)
沸点
222 °C/16 mmHg (lit.)
密度
1.24 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
ClP(=O)(c1ccccc1)c2ccccc2
InChI
1S/C12H10ClOP/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChI key
QPQGTZMAQRXCJW-UHFFFAOYSA-N
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应用
除了几种肽偶联剂之外，二苯基次膦酰氯（Ph2POCl）被广泛用作合成各种手性磷化氢双配位基配体（用于不对称合成）的前体。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1A
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
78.8 °F - closed cup
闪点(°C)
26 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Efficient syntheses of korupensamines A, B and michellamine B by asymmetric Suzuki-Miyaura coupling reactions.
Xu G, et al.
Journal of the American Chemical Society, 136(2), 570-573 (2013)
Kim, S.; Lee, P. H.; Lee, T. A. J.
Journal of the Chemical Society. Chemical Communications, 1242-1242 (1988)
Ramage, R.; Atrash, B. et al.
Journal of the Chemical Society. Perkin Transactions 1, 1617-1617 (1985)
Aboujaoude, E. E.; Lietje, S. et al.
Tetrahedron Letters, 26, 4435-4435 (1985)
Organophosphorus and nitro-substituted sulfonate esters of 1-hydroxy-7-azabenzotriazole as highly efficient fast-acting peptide coupling reagents.
Carpino L A, et al.
The Journal of Organic Chemistry, 69(1), 62-71 (2004)
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