质量水平
检测方案
99.999% trace metals basis
形式
powder and chunks
反应适用性
reagent type: catalyst
core: zinc
杂质
≤15.0 ppm Trace Metal Analysis
bp
~670 °C/1 atm (lit.)
mp
394 °C (lit.)
溶解性
diethyl ether: slightly soluble(lit.)
ethanol: very soluble(lit.)
SMILES字符串
Br[Zn]Br
InChI
1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChI key
VNDYJBBGRKZCSX-UHFFFAOYSA-L
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应用
二氧化硅或蒙脱石负载的溴化锌可用作 芳香族底物溴化反应的选择性催化剂。
它可作为起始原料用于制备聚氧化乙烯/锌盐系统， 该系统可用作聚合物电解质。
它也可用于制备氧化锌纳米颗粒。
它可作为起始原料用于制备聚氧化乙烯/锌盐系统， 该系统可用作聚合物电解质。
它也可用于制备氧化锌纳米颗粒。
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Franz, A.K. Woerpel, K.A.
Journal of the American Chemical Society, 121, 949-949 (1999)
Yasuhiro Inui et al.
Chemical & pharmaceutical bulletin, 57(10), 1158-1160 (2009-10-06)
Asymmetric intermolecular hydroacylation between salicylaldehyde (1) and 1,5-hexadiene (2) using a combination of [RhCl(C(8)H(14))(2)](2) (0.10 eq), (S)-BINAP (0.10 eq), and ZnBr(2) (0.20 eq) afforded an enantiomerically enriched hydroacylated product iso-3 of 84% ee, along with an achiral product normal-3.
J R Baker et al.
Organic letters, 9(1), 45-48 (2006-12-29)
[reaction: see text] A key structural feature of the Neocarzinostatin chromophore is a reactive epoxydiyne. We present here a new method for the preparation of epoxydiynes by the addition of an allenyl zinc bromide to a propargylic ketone.
Fernando Ferreira et al.
Nucleosides, nucleotides & nucleic acids, 24(5-7), 1009-1013 (2005-10-27)
An oligonucleotide protected with N-(trimethylsilyloxycarbonyl) (Teoc) and P-(trimethylsilylethanol) (Tse) groups was synthesized and deprotected by a single ZnBr2 treatment. Finally it was released from the solid support by cleavage of a disulfide linkage with TCEP. The olgonucleotide was obtained without
Yu Sung Chun et al.
Organic letters, 11(15), 3414-3417 (2009-07-04)
The in situ generated Blaise reaction intermediate, a zinc bromide complex of beta-enaminoester, reacts with various unactivated terminal alkynes and an internal alkyne under mild conditions to afford alpha-vinylated beta-enaminoesters in good to excellent yields.
商品
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
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