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线性分子式:
ZnI2
化学文摘社编号:
分子量:
319.20
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-396-0
MDL number:
Assay:
≥99.99% trace metals basis
Form:
crystalline
InChI key
UAYWVJHJZHQCIE-UHFFFAOYSA-L
InChI
1S/2HI.Zn/h2*1H;/q;;+2/p-2
SMILES string
I[Zn]I
assay
≥99.99% trace metals basis
form
crystalline
reaction suitability
core: zinc, reagent type: catalyst
impurities
≤100.0 ppm Trace Metal Analysis
mp
445 °C (lit.)
density
4.74 g/mL at 25 °C (lit.)
Quality Level
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General description
Zinc iodide is a faint yellow solid that absorbs water readily. It is synthesized using metallic zinc with an aqueous iodine solution. It is used as a Lewis acid for organic conversion.
Application
Zinc iodide can be used as:
- An electrolyte in Zinc-iodine redox flow batteries.
- An additive to prepare air-stable cationic lead perovskite films. The addition of ZnI2 enhances the film stability and photoluminescence without affecting the bandgap.
- As a precursor to prepare efficient, eco-friendly, and high color purity inkjet-printed blue InP/ZnS/ZnS quantum dot light-emitting diodes.
- A catalyst in promoting various chemical transformations, for example, in the direct synthesis of 2,3-Dihydroisoxazoles via a [3+2] cycloaddition reaction of the nitrones and terminal alkynes.
- An activator/initiator in living cationic polymerization reactions.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 2 Oral
target_organs
Thyroid
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Influence of type of zinc salts on photoinitiated living cationic polymerization of vinyl ethers
Muhammet U. Kahveci, et al.
Polymer, 54, 4798-4801 (2013)
Inkjet-printed blue InP/ZnS/ZnS quantum dot light-emitting diodes
Zhiwen Yang, et al.
Chemical Engineering Journal, 450, 138413-138413 (2022)
Metal?Organic Frameworks as Highly Active Electrocatalysts for High-Energy Density, Aqueous Zinc-Polyiodide Redox Flow Batteries
Bin Li, et al.
Nano Letters, 16, 4335-4340 (2016)
Air-Stable and Oriented Mixed Lead Halide Perovskite (FA/MA) by the One-Step Deposition Method Using Zinc Iodide and an Alkylammonium Additive
Loreta A. Muscarella, et al.},
ACS Applied Materials & Interfaces, 11, 17555-17562 (2019)
Zinc Iodide-Mediated Direct Synthesis of 2,3-Dihydroisoxazoles from Alkynes and Nitrones
Zu-Feng Xiao, et al.
advanced synthesis and catalysis, 358, 1859-1863 (2016)
商品
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
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