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Merck
CN

229474

碘化铋(III)

≥99.998% trace metals basis

别名:

三碘化铋, 三碘铋烷

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关于此项目

经验公式（希尔记法）:
BiI3
化学文摘社编号:
7787-64-6
分子量:
589.69
NACRES:
NA.23
PubChem Substance ID:
24853279
UNSPSC Code:
12352302
EC Number:
232-127-4
MDL number:
MFCD00010894
Assay:
≥99.998% trace metals basis
Form:
powder and chunks

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产品名称

碘化铋(III), ≥99.998% trace metals basis

InChI key

KOECRLKKXSXCPB-UHFFFAOYSA-K

InChI

1S/Bi.3HI/h;3*1H/q+3;;;/p-3

SMILES string

I[Bi](I)I

assay

≥99.998% trace metals basis

form

powder and chunks

reaction suitability

core: bismuth
reagent type: catalyst
core: bismuth

impurities

≤15.0 ppm Trace Metal Analysis

mp

408 °C (lit.)

density

5.78 g/mL at 25 °C (lit.)

application(s)

material synthesis precursor
perovskite solar cells

Quality Level

100

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相关类别

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX6739
0000355258
MKCW0603
MKCV4723
0000355258

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Mirko Scholz et al.
Physical chemistry chemical physics : PCCP, 20(16), 10677-10685 (2017-12-21)
Trivalent bismuth compounds featuring octahedral halide coordination, such as BiI3, double-perovskite structures and vacancy-ordered perovskite derivatives, have recently attracted considerable attention as potential environmentally benign thin film materials for solar light-harvesting and optoelectronic applications aiming to replace toxic lead-based perovskites.
Jie Sun et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 904-908 (2011-05-10)
A novel series of Ge-Te-BiI(3) chalcogenide glasses were prepared by traditional melt-quenching method and the glass-forming region was determined. Properties measurements including density, Vis-NIR and infrared (IR) transmission spectra with FTIR, XRD, DSC were adopted to analyze the composition, structure
Wenhua Bi et al.
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect
Yang Chen et al.
Physical chemistry chemical physics : PCCP, 13(13), 5659-5667 (2011-02-12)
The solvothermal reactions of BiI(3), KI, I(2), 4,4'-bipyridine (4,4'-bipy), and a small amount of water in alcohol and acetonitrile produced four bipyridinium iodobismuthates {[MQ](3)[Bi(2)I(6)(μ-I)(3)][Bi(2)I(6)(μ-I)(2)(MQ)(2)](3)} (1, MQ(+) = N-methyl-4,4'-bipyridinium), {[EQ](3)[Bi(2)I(6)(μ-I)(3)][Bi(2)I(6)(μ-I)(2)(EQ)(2)](3)} (2, EQ(+) = N-ethyl-4,4'-bipyridinium), [MV][BiI(5)] (Eur. J. Inorg. Chem., 2010, 5326)
Minhua Su et al.
Journal of hazardous materials, 229-230, 72-82 (2012-06-20)
BiOI-MWCNT composites, with high absorption and visible-light photocatalytic performance, were synthesized by a solvothermal process, in which ethylene glycol (EG) participated in the reaction. Synthesized BiOI-MWCNT composites were characterized by X-ray diffraction (XRD), diffuse reflectance spectra (DRS), scanning electronic microscopy
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