228931
氯化铈(III) 七水合物
99.9% trace metals basis
别名:
三氯化铈 七水合物
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关于此项目
线性分子式:
CeCl3 · 7H2O
化学文摘社编号:
分子量:
372.58
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-227-8
MDL number:
Assay:
99.9% trace metals basis
Form:
crystals and lumps
InChI key
KPZSTOVTJYRDIO-UHFFFAOYSA-K
InChI
1S/Ce.3ClH.7H2O/h;3*1H;7*1H2/q+3;;;;;;;;;;/p-3
SMILES string
[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ce](Cl)Cl
assay
99.9% trace metals basis
form
crystals and lumps
reaction suitability
core: cerium, reagent type: catalyst
impurities
≤1500.0 ppm Trace Rare Earth Analysis
density
~3.94 g/mL at 25 °C (lit.)
Quality Level
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General description
氯化铈(III)七水合物是吸湿性的晶体固体。它溶于水并形成酸性溶液。它用作各种应用中的铈源，如纳米金属氧化物合成和催化。
Application
氯化铈(III)七水合物可用于：
- 作为制备氧化铈纳米粒子的前体， 用于生物医学应用和光催化 降解。
- 作为溶液，通过喷雾热解法在玻璃基板上制备CeO2薄膜。
- 作为掺杂剂来制备ZnO和CeO2纳米晶体， 用于H2O2的电化学传感和 罗丹明B和刚果红染料的光催化降解。
- 作为添加剂，用于制备防腐配方和涂层。
- 用于合成碳纳米纤维复合材料， 以制造高温聚合物电解质膜燃料电池阴极。
- 作为硅胶上氯化铈(III)七水合物和碘化钠的组合的支持物，以促进Michael型加成。这些催化剂用于将吲哚和硝基烯烃转化为高产率的2-吲哚基-1-硝基烷烃衍生物。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Tetrahedron, 63, 892-892 (2007)
J. Chem. Res. (M), 668-668 (2006)
Xiaoming Tao et al.
Organic letters, 15(1), 72-75 (2012-12-25)
Dynamic kinetic resolution of various α-amido-β-keto phosphonates via asymmetric hydrogenation proceeded efficiently to give the corresponding β-hydroxy-α-amido phosphonates in high diastereo- and enantioselectivities (up to 99:1 syn/anti, 99.8% ee). The addition of catalytic amounts of CeCl(3)·7H(2)O is necessary to achieve
Na Li et al.
Environmental toxicology, 28(6), 349-358 (2011-06-10)
To investigate the molecular mechanism of inflammatory response in the mouse liver caused by exposure to CeCl₃, we measured the liver indices, and cerium content, evaluated the liver histopathological section, detected serum biochemical parameters of liver function, and the immunoglobulin
Yanfang Wu et al.
Chemosphere, 74(9), 1260-1265 (2008-12-17)
Using both histochemical and cytochemical methods, we investigated the effects of copper (Cu) on the production of hydrogen peroxide (H2O2) and superoxide anion (O2(.-)) in the leaves of the moss Plagiomnium cuspidatum. Cu treatment significantly increased the contents of total
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