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方案
97%
表单
liquid
折射率
n20/D 1.438 (lit.)
沸点
106-110 °C/9 mmHg (lit.)
密度
1.149 g/mL at 25 °C (lit.)
官能团
amine
ester
nitro
SMILES字符串
COC(=O)CCC[N+]([O-])=O
InChI
1S/C5H9NO4/c1-10-5(7)3-2-4-6(8)9/h2-4H2,1H3
InChI key
UBSPKGKFFQKZJB-UHFFFAOYSA-N
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一般描述
The reaction of methyl 4-nitrobutyrate with aldehydes, following the enantioselective Henry addition, was studied.
其他说明
残留物为 4-硝基戊酸甲酯
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
185.0 °F - closed cup
闪点(°C)
85 °C - closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
从最新的版本中选择一种:
分析证书(COA)
Organic letters, 12(13), 3058-3061 (2010-06-12)
A catalytic highly enantioselective Henry addition of methyl 4-nitrobutyrate to aldehydes using a Cu(II)-amino pyridine complex as catalyst is described. The products resulting from this reaction constitute a new, highly versatile family of chiral building blocks as a result of
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