所有图片(3)
About This Item
线性分子式:
[CH3COCH=C(O-)CH3]2MoO2
CAS号:
分子量:
326.15
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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表单
powder
质量水平
反应适用性
core: molybdenum
reagent type: catalyst
mp
184 °C (dec.) (lit.)
储存温度
2-8°C
SMILES字符串
CC(=O)\C=C(\C)O[Mo](=O)(=O)O\C(C)=C/C(C)=O
InChI
1S/2C5H8O2.Mo.2O/c2*1-4(6)3-5(2)7;;;/h2*3,6H,1-2H3;;;/q;;+2;;/p-2/b2*4-3-;;;
InChI key
SKMUJBBRXZPAJY-VGKOASNMSA-L
一般描述
二（乙酰丙酮）氧化钼(VI) 可用作氧化转化反应的起始原料和催化剂。
应用
双（乙酰丙酮）二氧化钼（VI）可用于：
- 作为原材料，合成二氧化钼（VI）席夫（Schiff）碱配合物，此配合物作为催化剂，可用H2O2氧化醇。
- 制备氧化石墨烯负载的多相钼基催化剂，用于烯烃的环氧化。
- 作为催化剂，用于硫醇和醇的醚化反应和硫醚化反应。
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Peter Priecel et al.
Frontiers in chemistry, 8, 216-216 (2020-04-24)
This investigation deals with NiMo-alumina hydrotreating catalysts effective in the deoxygenation of rapeseed oil. The main goal was to compare catalyst structure and their deoxygenation performance and to link these parameters to reveal important structural information regarding the catalyst's intended
Covalent functionalization of graphene oxide with molybdenum-carboxylate complexes: new reusable catalysts for the epoxidation of olefins
Masteri-Farahani M and Mirshekar S
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 538(1), 387-392 (2018)
Dutta, S.k. et al.
Inorganic Chemistry, 36, 2517-2517 (1997)
Silica-supported molybdenum complex: a novel, selective and reusable organic--inorganic hybrid catalyst for eco-friendly oxidation of sulfides and olefins
Sharma RK, et al.
Polyhedron, 45(1), 86-93 (2012)
Molybdenum (VI)-catalyzed dehydrative construction of CO and CS bonds formation via etherification and thioetherification of alcohols and thiols
Singh RR, et al.
Molecular Catalysis, 492(1), 110954-110954 (2020)
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