质量水平
检测方案
98%
形式
powder
反应适用性
reagent type: catalyst
core: silver
SMILES字符串
[Ag+].F[Sb-](F)(F)(F)(F)F
InChI
1S/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6
InChI key
GSXFODUDOAXUBF-UHFFFAOYSA-H
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应用
可形成稳定的阳离子自由基盐,并作为环氧化物开环反应和亚磺酰化反应的酸性催化剂。用于制备 3,3′-二氰基二苯基乙炔银配位网络,以研究配体对网络结构的作用,以便研制新型材料。
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Chemistry Letters (Jpn), 1901-1901 (1992)
Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles.
Journal of the American Chemical Society, 129(26), 8060-8061 (2007-06-09)
The Journal of Organic Chemistry, 57, 6178-6178 (1992)
Chemistry Letters (Jpn), 1-1 (1993)
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar
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