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Merck
CN

227692

Sigma-Aldrich

三氧化硫

contains stabilizer, ≥99%

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别名:
硫酸酐
线性分子式:
SO3
CAS号:
分子量:
80.06
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:

蒸汽密度

2.8 (vs air)

蒸汽压

280 mmHg ( 25 °C)

检测方案

≥99%

形式

liquid

包含

stabilizer

反应适用性

reagent type: oxidant

杂质

low-melting solid polymer (the formation of which is unavoidable)

bp

44.7 °C (lit.)

mp

16.8 °C (lit.)

密度

1.97 g/mL at 25 °C (lit.)

SMILES字符串

O=S(=O)=O

InChI

1S/O3S/c1-4(2)3

InChI key

AKEJUJNQAAGONA-UHFFFAOYSA-N

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一般描述

三氧化硫是硫的一种氧化物,在含硫燃料燃烧过程中释放出来。它可在钒催化剂存在下通过二氧化硫氧化制备。

应用

三氧化硫可用于通过磺化甲烷合成甲磺酸 (MSA),也可用于通过与氟烯烃反应合成氟化 β-砜。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

靶器官

Respiratory system

补充剂危害

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles

法规信息

新产品

分析证书(COA)

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. Is Product 227692, Sulfur trioxide, OK to use if it contains solids?

    This product may contain low-melting solid polymer, which is unavoidable. If the material is not completely liquid, place the bottle in a glass beaker or metal pail and warm under heat lamp or in an oven at 35°C. DO NOT OVERHEAT! This product boils at 44.7°C. Melting may take up to one week. When the material is liquid, it is ready for use.

  5. What is the stabilizer used in Product 227692, Sulfur trioxide?

    The manufacturer considers the identity of the stabilizer to be proprietary information.

  6. Why does Product 227692, Sulfur trioxide, contain a stabilizer?

    The stabilizer is present to facilitate melting, not to prevent polymerization.

  7. How is Product 227692, Sulfur trioxide, packaged?

    This product is packaged in a screw-capped glass bottle.

  8. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  9. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Fluorinated ?-Sultones.
Knunyants IL & Sokolski GA
Angewandte Chemie (International Edition in English), 11(7), 583-595 null
Direct sulfonation of methane to methanesulfonic acid by sulfur trioxide catalyzed by cerium (IV) sulfate in the presence of molecular oxygen.
Mukhopadhyay S and Bell AT
Advanced Synthesis & Catalysis, 346(8), 913-916 (2004)
Emissions of sulfur trioxide from coal-fired power plants.
Srivastava RK, et al.
Journal of the Air & Waste Management Association (1995), 54(6), 750-762 (2004)
Wei Liu et al.
Journal of agricultural and food chemistry, 58(1), 172-179 (2009-12-17)
The sulfation of psyllium was carried out with sulfur trioxide-pyridine in dimethyl formamide. Three sulfated psyllium derivatives, named SP1, SP2, and SP3, were characterized by sulfur content determination, elemental analysis, FT-IR, and surface charge analysis. The sulfated derivatives were also
T Kapias et al.
Journal of hazardous materials, 67(1), 9-40 (1999-05-20)
A new model describing the dispersion behaviour and the processes that occur in a cloud generated from accidental spills of SO3 and oleum has been developed. Such a cloud may initially behave as a dense gas, with several chemical and

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