226637
亚硝酸丁酯
95%
别名:
亚硝酸正丁酯
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线性分子式:
CH3(CH2)3ONO
化学文摘社编号:
分子量:
103.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-862-1
Beilstein/REAXYS Number:
1701036
MDL number:
产品名称
亚硝酸丁酯, 95%
InChI key
JQJPBYFTQAANLE-UHFFFAOYSA-N
InChI
1S/C4H9NO2/c1-2-3-4-7-5-6/h2-4H2,1H3
SMILES string
CCCCON=O
vapor pressure
760 mmHg ( 78 °C)
assay
95%
form
liquid
refractive index
n20/D 1.376 (lit.)
bp
78 °C (lit.)
solubility
alcohol: miscible(lit.)
diethyl ether: miscible(lit.)
density
0.882 g/mL at 25 °C (lit.)
functional group
O-nitroso
nitroso
storage temp.
2-8°C
Quality Level
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General description
亚硝酸丁酯的光解离动力学的通过时间分辨傅立叶变换红外（TR-FTIR）发射光谱进行了研究。亚硝酸丁酯对甲基维生素B12和5-甲基四氢叶酸的影响已有研究。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
8.6 °F - closed cup
flash_point_c
-13 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
E Roth et al.
American journal of hematology, 20(2), 153-159 (1985-10-01)
The use of volatile butylnitrite in place of sodium nitrite for the in vitro production of methemoglobin was explored in studies of G6PD-deficient red cells and for measurements of the red cell methemoglobin reductase activity. It was found that butylnitrite
Tsuyoshi Taniguchi et al.
Chemical communications (Cambridge, England), 49(22), 2198-2200 (2013-02-12)
A method for direct functionalization of three positions including an unactivated C-H bond of aliphatic alkenes using tert-butyl nitrite and molecular oxygen to give γ-lactols has been developed. The present reaction proceeds through a sequence of radical processes involving oxynitration
Dipankar Koley et al.
Organic letters, 11(18), 4172-4175 (2009-08-25)
tert-Butyl nitrite was identified as a safe and chemoselective nitrating agent that provides preferentially mononitro derivatives of phenolic substrates in the presence of potentially competitive functional groups. On the basis of our control experiments, we propose that the reaction proceeds
J D Osterloh et al.
Journal of pharmaceutical sciences, 74(7), 780-782 (1985-07-01)
The uptake of butyl nitrite by rats (500 g, one rat/chamber) was determined over a 5-min exposure period. About 44% of the starting amount (771-3855 ppm) of n-butyl nitrite was consumed in 5 min. Three rats per exposure concentration were
B A Meloche et al.
Xenobiotica; the fate of foreign compounds in biological systems, 23(8), 863-871 (1993-08-01)
1. The addition of n-butyl nitrite (BN) to isolated rat hepatocytes caused rapid S-nitrosyl glutathione (GSNO) formation, then a concomitant decrease in protein thiols, followed by a marked ATP depletion. Cytotoxic concentrations of BN also caused lipid peroxidation after a
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