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Merck
CN

226637

Sigma-Aldrich

亚硝酸丁酯

95%

别名:

亚硝酸正丁酯

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About This Item

线性分子式:
CH3(CH2)3ONO
CAS号:
分子量:
103.12
Beilstein:
1701036
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

760 mmHg ( 78 °C)

质量水平

方案

95%

表单

liquid

折射率

n20/D 1.376 (lit.)

沸点

78 °C (lit.)

溶解性

alcohol: miscible(lit.)
diethyl ether: miscible(lit.)

密度

0.882 g/mL at 25 °C (lit.)

官能团

O-nitroso
nitroso

储存温度

2-8°C

SMILES字符串

CCCCON=O

InChI

1S/C4H9NO2/c1-2-3-4-7-5-6/h2-4H2,1H3

InChI key

JQJPBYFTQAANLE-UHFFFAOYSA-N

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一般描述

亚硝酸丁酯的光解离动力学的通过时间分辨傅立叶变换红外(TR-FTIR)发射光谱进行了研究。亚硝酸丁酯对甲基维生素B12和5-甲基四氢叶酸的影响已有研究

象形图

FlameSkull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

8.6 °F - closed cup

闪点(°C)

-13 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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E Roth et al.
American journal of hematology, 20(2), 153-159 (1985-10-01)
The use of volatile butylnitrite in place of sodium nitrite for the in vitro production of methemoglobin was explored in studies of G6PD-deficient red cells and for measurements of the red cell methemoglobin reductase activity. It was found that butylnitrite
Dipankar Koley et al.
Organic letters, 11(18), 4172-4175 (2009-08-25)
tert-Butyl nitrite was identified as a safe and chemoselective nitrating agent that provides preferentially mononitro derivatives of phenolic substrates in the presence of potentially competitive functional groups. On the basis of our control experiments, we propose that the reaction proceeds
Tsuyoshi Taniguchi et al.
Chemical communications (Cambridge, England), 49(22), 2198-2200 (2013-02-12)
A method for direct functionalization of three positions including an unactivated C-H bond of aliphatic alkenes using tert-butyl nitrite and molecular oxygen to give γ-lactols has been developed. The present reaction proceeds through a sequence of radical processes involving oxynitration
J D Osterloh et al.
Journal of pharmaceutical sciences, 74(7), 780-782 (1985-07-01)
The uptake of butyl nitrite by rats (500 g, one rat/chamber) was determined over a 5-min exposure period. About 44% of the starting amount (771-3855 ppm) of n-butyl nitrite was consumed in 5 min. Three rats per exposure concentration were
G R Newell et al.
The American journal of medicine, 78(5), 811-816 (1985-05-01)
Early reports of the acquired immune deficiency syndrome (AIDS) in homosexual men suggested that the cause might be related to homosexual life-style practices, including use of recreational drugs. Inhalation of volatile nitrites is a possible contributing factor in AIDS because

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