226157
N-羟基氨基甲酸叔丁酯
≥98%
别名:
N-叔丁氧羰基羟胺
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关于此项目
线性分子式:
(CH3)3COCONHOH
化学文摘社编号:
分子量:
133.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-836-2
Beilstein/REAXYS Number:
1756546
MDL number:
产品名称
N-羟基氨基甲酸叔丁酯, ≥98%
InChI key
DRDVJQOGFWAVLH-UHFFFAOYSA-N
InChI
1S/C5H11NO3/c1-5(2,3)9-4(7)6-8/h8H,1-3H3,(H,6,7)
SMILES string
CC(C)(C)OC(=O)NO
assay
≥98%
form
solid
mp
53-55 °C (lit.)
functional group
amine
storage temp.
2-8°C
Quality Level
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存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Useful hydroxylamine derivatives for the synthesis of hydroxamic acids.
Tetrahedron Letters, 33(35), 5055-5058 (1992)
Synthetic Communications, 22, 2579-2579 (1992)
Brian S Bodnar et al.
The Journal of organic chemistry, 72(10), 3929-3932 (2007-04-14)
The addition of azides to acylnitroso hetero-Diels-Alder cycloadducts derived from cyclopentadiene affords exo-triazolines in excellent yield. The reaction is greatly affected by the level of alkene strain, while sterically demanding azides do not hinder the reaction. Conversion of the triazolines
Tetrahedron Letters, 33, 5055-5055 (1992)
M J Lee et al.
Journal of medicinal chemistry, 35(20), 3648-3652 (1992-10-02)
In the preceding paper, analogs of chlorpropamide with an OMe substituent on the sulfonamide nitrogen were shown to inhibit aldehyde dehydrogenase (AlDH), and it was postulated that these compounds were bioactivated by O-demethylation to release nitroxyl (HN = O, nitrosyl
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