质量水平
检测方案
98%
形式
solid
mp
42-50 °C (lit.)
密度
4.416 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
BrI
InChI
1S/BrI/c1-2
InChI key
CBEQRNSPHCCXSH-UHFFFAOYSA-N
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一般描述
单溴化碘是一种卤素间化合物，在合成聚酮结构单元时用作亲电试剂。
单溴化碘（IBr）是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化，以及高烯丙基碳酸酯的非对映选择性环化。
单溴化碘（IBr）是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化，以及高烯丙基碳酸酯的非对映选择性环化。
应用
一种合成聚酮结构单元的新方法中所用的亲电试剂。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
The Thermodynamic Constants of Iodine Monobromide
McMorris, et al.
Journal of the American Chemical Society, 53, 2625-2631 (1931)
Kai Liu et al.
Organic letters, 8(23), 5393-5395 (2006-11-03)
[Structure: see text] A strategically novel approach to the formation of syn-1,3-diol mono- and diethers through electrophilic activation of homoallylic alkoxymethyl ethers has been developed. The resulting polyketide-like synthetic fragments are generated in good yield and with excellent stereocontrol. A
Iodine Monobromide
Brisbois RG, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-5 (2001)
Peter Imming et al.
Archiv der Pharmazie, 335(9), 449-451 (2002-11-26)
The iodine value (iodine number) is an important analytical characteristic of fats and oils. Leading pharmacopeias determine it using iodine monobromide (Hanus method). We used methyl oleate as a simple analog of unsaturated triacylglycerols to identify the products. After performing
L E Mikhno et al.
Likars'ka sprava, (1)(1), 89-91 (1992-01-01)
The effect of local iodine-bromine baths at the early stage of health-resort treatment on the main values of the cardio-vascular system was studied in patients suffering of myocardial infarction with arterial hypertension. It was established that local iodine-bromine baths produce
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