224839
氯化铋 (III)
reagent grade, ≥98%
别名:
三氯化铋, 三氯铋
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关于此项目
经验公式（希尔记法）:
BiCl3
化学文摘社编号:
分子量:
315.34
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-123-2
MDL number:
Assay:
≥98%
Grade:
reagent grade
Form:
powder, chunks or granules
产品名称
氯化铋 (III), reagent grade, ≥98%
InChI key
JHXKRIRFYBPWGE-UHFFFAOYSA-K
InChI
1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
SMILES string
Cl[Bi](Cl)Cl
grade
reagent grade
assay
≥98%
form
powder, chunks or granules
reaction suitability
reagent type: catalyst
core: bismuth
bp
447 °C (lit.)
mp
230-232 °C (lit.)
Quality Level
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Application
氯化铋 (III) 可作为催化剂用于以下过程：
- 醇解、乙酰化和环氧化物水解生成相应的的 β-烷氧基和 β-乙酰氧基醇和二醇。
- 用硫氰酸铵从环氧乙烷制备噻吩。
- 羰基化合物、胺和亚磷酸二烷基酯三组分偶联生成 α-氨基膦酸盐。
- 烯丙基三甲基硅烷与仲苯甲醇的烯丙基化反应。
- [4 + 2] 二烯烃与α-羰基烯二烯烃之间的环加成反应。
General description
氯化铋 (III) 是一种无机盐，可由铋与氯反应制得。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Daintith J
The facts on file dictionary of chemistry, 28-28 (2014)
Bismuth (III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane
De SK & Gibbs RA.
Tetrahedron Letters, 46(48), 8345-8350 (2005)
Bismuth (III) chloride (BiCl3)-An efficient catalyst for mild, regio-and stereoselective cleavage of epoxides with alcohols, acetic Acid and water.
Mohammadpoor-Baltork I.
Synthetic Communications, 30(13), 2365-2374 (2000)
Bismuth (III) Chloride-Catalyzed Three-Component Coupling: Synthesis of a-Amino Phosphonates.
Zhan ZP and Li JP.
Synthetic Communications, 35(19), 2501-2508 (2005)
Bismuth (iii) Chloride Mediated Michaelis-Arbuzov Reaction: A Facile Synthesis of Substituted Arylphosphonates/Phosphinates and Bioactivity Evaluation.
Subramanyam C, et al.
Phosph. Sulfur Relat. Elem. (2015)
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