所有图片(1)
别名:
Copper dilithium tetrachloride, Dilithium tetrachlorocuprate(2-), Lithium Tetrachlorocuprate
线性分子式:
Li2CuCl4
CAS号:
分子量:
219.24
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
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形式
liquid
质量水平
反应适用性
reagent type: catalyst
core: copper
浓度
0.1 M in THF
密度
0.91 g/mL at 25 °C
SMILES字符串
[Li+].[Li+].Cl[Cu--](Cl)(Cl)Cl
InChI
1S/4ClH.Cu.2Li/h4*1H;;;/q;;;;+2;2*+1/p-4
InChI key
HCJWWBBBSCXJMS-UHFFFAOYSA-J
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应用
用于卤代烷与烷基格氏试剂偶联反应的催化剂。
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Respiratory system
补充剂危害
WGK
WGK 2
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
K Minamoto et al.
Nucleic acids symposium series, (27)(27), 109-110 (1992-01-01)
The reaction of 1-(2,3-anhydro-5-O-trityl-beta-D-lyxofuranosyl)-2-O-methyluracil (1a) and its thymine analogue (1b) with dilithium tetrahalocuprate (Li2CuX4) revealed excellent to perfect regioselectivity, yielding 2,2'-anhydro-3'-halonucleosides (2a-d), while the same reactions with 2,3-anhydro uracil and thymine nucleosides (4a,b) gave arabinosyl (5a-d) and xylosyl halohydrins (6a-d)
Tetrahedron, 62, 4851-4851 (2006)
Kenji Mori
Bioscience, biotechnology, and biochemistry, 74(3), 595-600 (2010-03-09)
A mixture of the four stereoisomers of 1,7-dimethylnonyl propanoate, the female sex pheromone of the western corn rootworm (Diabrotica virgifera virgifera LeConte), was synthesized in four different ways by employing one of the following four reactions as the key step:
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