224294
硫代磷酰氯
98%
别名:
三氯硫磷, 硫代氯化磷酰
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关于此项目
线性分子式:
PSCl3
化学文摘社编号:
分子量:
169.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
223-622-6
MDL number:
Assay:
98%
Form:
liquid
InChI key
WQYSXVGEZYESBR-UHFFFAOYSA-N
InChI
1S/Cl3PS/c1-4(2,3)5
SMILES string
ClP(Cl)(Cl)=S
assay
98%
form
liquid
refractive index
n20/D 1.555 (lit.)
bp
125 °C (lit.)
mp
−35 °C (lit.)
solubility
benzene: soluble(lit.), carbon disulfide: soluble(lit.), carbon tetrachloride: soluble(lit.), chloroform: soluble(lit.)
density
1.668 g/mL at 25 °C (lit.)
Quality Level
Application
Thiophosphoryl chloride was used in the synthesis of O-ethyl dichlorothiophosphate.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Wen Jun Gui et al.
Analytical biochemistry, 357(1), 9-14 (2006-08-22)
Two haptens of the insecticide triazophos (O,O-diethyl O-[1-phenyl-1H-1,2,4-triazol-3-yl] phosphorothioate) were synthesized by introducing appropriate spacers in the O-ethyl site of the analyte molecular structure. First, thiophosphoryl chloride (PSCl(3)) reacts with methanol at low temperature to give O-ethyl dichlorothiophosphate. After reacting
Mohammed D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(8), 1577-1582 (2002-08-09)
A new route has been devised, leading to the production of phosphorus thiotrihalides, SPX3 where X = F, Br and I by an on-line process using phosphorus thiotrichloride, SPCl3 as starting compound gassed over the following heated salts NaF, KBr
[Hygienic substantiation of the maximum permissible level of phosphorus thiotrichloride in reservoir water].
V M Tomkiv
Gigiena i sanitariia, (11)(11), 68-70 (1988-11-01)
Sarah E Lee et al.
Chembiochem : a European journal of chemical biology, 12(4), 633-640 (2011-02-10)
The elucidation of signalling pathways relies heavily upon the identification of protein kinase substrates. Recent investigations have demonstrated the efficacy of chemical genetics using ATP analogues and modified protein kinases for specific substrate labelling. Here we combine N(6) -(cyclohexyl)ATPγS with
Sebastian Golojuch et al.
Bioorganic & medicinal chemistry, 28(13), 115523-115523 (2020-05-05)
Eukaryotic translation initiation factor 4E (eIF4E) is overexpressed in many cancers deregulating translational control of the cell cycle. mRNA 5' cap analogs targeting eIF4E are small molecules with the potential to counteract elevated levels of eIF4E in cancer cells. However
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