224286
4-甲基吗啡-N-氧化物
97%
别名:
NMO
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关于此项目
经验公式（希尔记法）:
C5H11NO2
化学文摘社编号:
分子量:
117.15
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
231-391-8
Beilstein/REAXYS Number:
507437
MDL number:
产品名称
4-甲基吗啡-N-氧化物, 97%
InChI key
LFTLOKWAGJYHHR-UHFFFAOYSA-N
InChI
1S/C5H11NO2/c1-6(7)2-4-8-5-3-6/h2-5H2,1H3
SMILES string
C[N+]1([O-])CCOCC1
assay
97%
reaction suitability
reagent type: oxidant
mp
180-184 °C (lit.)
functional group
ether
storage temp.
2-8°C
Quality Level
Application
用于酮的硅氰化反应的非金属催化剂。用于离子液体中 Sharpless 不对称双羟基化反应的助氧化剂。
General description
N-甲基吗啉N氧化物是一种有机化合物，在有机合成中与 OsO4和钌酸盐一起用作共氧化剂。在最近的研究中，其已用作醛酮硅氰化反应的催化剂。绿色纤维（Lyocell）是一种再生纤维素纤维，可由N-甲基吗啉N氧化物通过环保方式制得。
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Repr. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Synlett, 6, 1077-1079 (2004)
Luís C Branco et al.
The Journal of organic chemistry, 69(13), 4381-4389 (2004-06-19)
The use of room-temperature ionic liquids (RTILs) in the Sharpless catalytic asymmetric dihydroxylation (AD) as a cosolvent or replacement of the tert-butanol was studied in detail by screening 11 different RTILs. The AD reaction is faster in 1-n-butyl-3-methylimidazolium hexafluorophosphate [C(4)mim][PF(6)]
N?Methylmorpholine N?Oxide
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2008)
Marzieh Shafiei et al.
Bioresource technology, 102(17), 7879-7886 (2011-06-21)
Given that N-methylmorpholine-N-oxide (NMMO) is a promising alternative for the pretreatment of lignocelluloses, a novel process for ethanol and biogas production from wood was developed. The solvent, NMMO, is concentrated by multistage evaporation, and the wood is pretreated with the
The N-Methylmorpholine-N-Oxide (NMMO) Process of Producing Regenerated Fibers
Innovative Biofibers from Renewable Resources (2014)
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