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Merck
CN

22135

Sigma-Aldrich

(+)-雪松醇

≥99.0% (sum of enantiomers, GC)

别名:

(1S,2R,5S,7R,8R)-2,6,6,8-四甲基三环[5.3.1.01.5]十一烷-8-醇

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About This Item

经验公式(希尔记法):
C15H26O
CAS号:
分子量:
222.37
Beilstein:
2206347
EC 号:
MDL编号:
UNSPSC代码:
12352212
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

≥99.0% (sum of enantiomers, GC)

表单

solid

旋光性

[α]20/D +10.5±1°, c = 5% in chloroform

沸点

273 °C (lit.)

mp

82-86 °C
86-87 °C (lit.)

官能团

hydroxyl

SMILES字符串

C[C@@H]1CC[C@H]2C(C)(C)[C@H]3C[C@@]12CC[C@@]3(C)O

InChI

1S/C15H26O/c1-10-5-6-11-13(2,3)12-9-15(10,11)8-7-14(12,4)16/h10-12,16H,5-9H2,1-4H3/t10-,11+,12-,14-,15+/m1/s1

InChI key

SVURIXNDRWRAFU-OGMFBOKVSA-N

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一般描述

(+)-雪松醇是α-雪松烯的结晶水合产物,雪松烯是雪松木油中发现的倍半萜烯。它可以用作化妆品,洗发水和肥皂中的香料成分,也可以用作非化妆品,例如清洁剂和洗涤剂。(±)雪松醇可以通过烷基环戊二烯的分子内Diels-Alder反应合成。

应用

(+)-雪松醇可用作在酸催化剂存在下使用乙酸酐乙酰化制备乙酸雪松酯的起始原料。它也可以作为通过选择性C-H键官能化全合成稀有八角倍半萜(+)-假茴香苷的前体掺入。

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Total synthesis of (.+-.)-cedrol and (.+-.)-cedrene via an intramolecular Diels-Alder reaction
Breitholle EG and Fallis AG
The Journal of Organic Chemistry, 43(10), 1964-1968 (1978)
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Larviciding is an effective supplementary tool for malaria vector control, but the identification and accessibility of aquatic habitats impedes application. Dissemination of the insect growth regulator, pyriproxyfen (PPF), by gravid Anopheles might constitute a novel application strategy. This study aimed
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A previous study reported that when cedrol (odorant) is inhaled directly through the lower airway of the trachea, it decreases the sympathetic nervous activity and blood pressure in totally laryngectomized subjects (Umeno et al., 2008). In the present study, totally

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