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质量水平
方案
≥97%
表单
liquid
折射率
n20/D 1.473 (lit.)
沸点
100-101 °C/23 mmHg (lit.)
密度
0.852 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(C)(C)c1cccc(n1)C(C)(C)C
InChI
1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3
InChI key
UWKQJZCTQGMHKD-UHFFFAOYSA-N
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一般描述
2,6-二--叔 -丁基吡啶与四苯基卟啉铁阳离子自由基的反应性已通过质子 NMR 光谱学进行了研究。2,6-二- 叔 -丁基吡啶与碘甲烷和氟磺酸甲酯在高压下的反应已有报道。
应用
以 2,6-二- 叔 叔丁基吡啶为质子捕获剂,研究了异丁烯的活性聚合。并与硝酸铈铵在 α-醛的烯醇化生成 1,4-二羰基系统。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
159.8 °F - closed cup
闪点(°C)
71 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Reactions of crowded molecules under high pressure. Reactions of 2, 6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure.
Okamoto Y and Lee KI.
Journal of the American Chemical Society, 97(!4), 4015-4018 (1975)
Karolina A Tarach et al.
ChemSusChem, 12(3), 633-638 (2018-12-07)
A new theoretical and practical framework has been developed through operando study of the zeolite catalytic cracking of low-density polyethylene (as a model reaction) under reaction conditions. Results show that microporous ZSM-5 gives rise to less cracking products. Hierarchical ZSM-5
J. Macromol. Sci., Pure Appl. Chem., A29, 639-639 (1992)
Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes.
Hye-Young Jang et al.
Journal of the American Chemical Society, 129(22), 7004-7005 (2007-05-15)
Living carbocationic polymerization of isobutylene with blocked bifunctional initiators in the presence of di-tert-butylpyridine as a proton trap.
Gyor M, et al.
J. Macromol. Sci., Pure Appl. Chem., 29(8), 639-653 (1992)
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