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Merck
CN

219584

2,6-二叔丁基吡啶

≥97%

别名:

2,6-二叔丁基吡啶, 2,6-双(1,1-二甲基乙基)吡啶

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关于此项目

经验公式(希尔记法):
C13H21N
化学文摘社编号:
分子量:
191.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-557-6
Beilstein/REAXYS Number:
125886
MDL number:
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产品名称

2,6-二叔丁基吡啶, ≥97%

assay

≥97%

form

liquid

InChI key

UWKQJZCTQGMHKD-UHFFFAOYSA-N

InChI

1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3

SMILES string

CC(C)(C)c1cccc(n1)C(C)(C)C

refractive index

n20/D 1.473 (lit.)

bp

100-101 °C/23 mmHg (lit.)

density

0.852 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

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Application

以 2,6-二- 叔丁基吡啶为质子捕获剂,研究了异丁烯的活性聚合。并与硝酸铈铵在 α-醛的烯醇化生成 1,4-二羰基系统

General description

2,6-二--叔 -丁基吡啶与四苯基卟啉铁阳离子自由基的反应性已通过质子 NMR 光谱学进行了研究。2,6-二--丁基吡啶与碘甲烷和氟磺酸甲酯在高压下的反应已有报道

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Reactions of crowded molecules under high pressure. Reactions of 2, 6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure.
Okamoto Y and Lee KI.
Journal of the American Chemical Society, 97(!4), 4015-4018 (1975)
Karolina A Tarach et al.
ChemSusChem, 12(3), 633-638 (2018-12-07)
A new theoretical and practical framework has been developed through operando study of the zeolite catalytic cracking of low-density polyethylene (as a model reaction) under reaction conditions. Results show that microporous ZSM-5 gives rise to less cracking products. Hierarchical ZSM-5
J. Macromol. Sci., Pure Appl. Chem., A29, 639-639 (1992)
Krystyna Rachlewicz et al.
Inorganic chemistry, 35(5), 1136-1147 (1996-02-28)
The reactivity of iron(III) tetraphenylporphyrin pi-cation radical (TPP(*))Fe(III)(ClO(4))(2), (1-1) iron(III) tetra-p-tolylporphyrin pi-cation radical (TTP(*))Fe(III)(ClO(4))(2) (1-2) and iron(III) tetramesitylporphyrin pi-cation radical (TMP(*))Fe(III)(ClO(4))(2) (1-3) complexes with 2,4,6-collidine, 2,3,6-collidine, 2-picoline, 2,6-di-tert-butylpyridine, and 2,6-dibromopyridine has been examined by (1)H NMR spectroscopy in dichloromethane-d(2) solution
Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes.
Hye-Young Jang et al.
Journal of the American Chemical Society, 129(22), 7004-7005 (2007-05-15)

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