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219533

Sigma-Aldrich

1-硝基-1-环己烯

99%

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About This Item

经验公式（希尔记法）:
C6H9NO2
CAS号:
2562-37-0
分子量:
127.14
EC 号:
219-883-0
MDL编号:
MFCD00001540
UNSPSC代码:
12352100
PubChem化学物质编号:
24853132
NACRES:
NA.22

质量水平

100

方案

99%

表单

liquid

折射率

n20/D 1.505 (lit.)

沸点

66-68 °C/1.5 mmHg (lit.)

密度

1.127 g/mL at 25 °C (lit.)

官能团

nitro

储存温度

2-8°C

SMILES字符串

[O-][N+](=O)C1=CCCCC1

InChI

1S/C6H9NO2/c8-7(9)6-4-2-1-3-5-6/h4H,1-3,5H2

InChI key

DJBRXNRKYAWTBL-UHFFFAOYSA-N

相关类别

一般描述

1-硝基-1-环己烯的化学选择性氢化是由负载在TiO2或Fe2O3上的金纳米粒子所催化的。

应用

1-硝基-1-环己烯可通过负载的金纳米粒子（Au/TiO2及Au/Fe2O3）所催化的化学选择性加氢用于制备取代苯胺。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H319

危险分类

Eye Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

174.2 °F - closed cup

闪点(°C)

79 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW5379
MKCK2505
MKCF0980
MKBZ9311V
MKBW2599V

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Avelino Corma et al.
Nature protocols, 1(6), 2590-2595 (2007-04-05)
A protocol for the chemoselective hydrogenation of nitro compounds to the corresponding anilines by means of supported gold catalysts is described. Nitro groups on different compounds--containing double bonds, carbonyl, nitrile or amide groups--have been successfully hydrogenated on supported gold nanoparticles
Avelino Corma et al.
Science (New York, N.Y.), 313(5785), 332-334 (2006-07-22)
The selective reduction of a nitro group when other reducible functions are present is a difficult process that often requires stoichiometric amounts of reducing agents or, if H2 is used, the addition of soluble metals. Gold nanoparticles supported on TiO2
Fabian Niedermair et al.
Inorganic chemistry, 49(20), 9333-9342 (2010-09-16)
A series of π-extended phosphorescent palladium(II) and platinum(II) porphyrin complexes were synthesized, in which additional benzene rings are fused radially onto at least one of the four peripheral benzo groups. The photophysical properties of the metalloporphyrins palladium(II)-meso-tetra-(4-fluorophenyl)mononaphthotribenzoporphyrin (Pd1NF), cis-palladium(II)-meso-tetra-(4-fluorophenyl)dibenzodinaphthoporphyrin (Pd2NF)

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