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Merck
CN

218790

Sigma-Aldrich

氯化四苯磷

98%

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别名:
Chlorotetraphenylphosphorane
线性分子式:
(C6H5)4P(Cl)
CAS号:
分子量:
374.84
Beilstein:
3922393
EC 号:
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

solid

mp

272-274 °C (lit.)

SMILES字符串

[Cl-].c1ccc(cc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1

InChI key

WAGFXJQAIZNSEQ-UHFFFAOYSA-M

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应用

  • 四苯基氯化膦可用于调节 CH 3NH3PbI3 薄膜在沉积过程中的结晶度,以提高钙钛矿型太阳能电池 (PSCs) 器件的性能。
  • 与有机金属阴离子络合物反应生成相应的盐。
  • 在钯催化的 Heck 反应中也可作为芳基化试剂。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Tetraarylphosphonium Halides as Arylating Reagents in Pd?Catalyzed Heck and Cross?Coupling Reactions.
Hwang L K, et al.
Angewandte Chemie (International Edition in English), 44(38), 6166-6169 (2005)
Fedor F Severin et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(2), 663-668 (2010-01-19)
A unique phenomenon of mitochondria-targeted protonophores is described. It consists in a transmembrane H(+)-conducting fatty acid cycling mediated by penetrating cations such as 10-(6'-plastoquinonyl)decyltriphenylphosphonium (SkQ1) or dodecyltriphenylphosphonium (C(12)TPP). The phenomenon has been modeled by molecular dynamics and directly proved by
Toshiaki Hattori et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 878(3-4), 477-480 (2009-12-17)
Five chitosan oligosaccharides were separated in acidic aqueous solution by capillary electrophoresis (CE) with indirect photometric detection using a positively coated capillary. Electrophoretic mobility of the chitooligosaccharides (COSs) depended on the number of monomer units in acidic aqueous solution, similar

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