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Merck
CN

218790

氯化四苯磷

98%, solid

别名:

Chlorotetraphenylphosphorane

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关于此项目

线性分子式:
(C6H5)4P(Cl)
化学文摘社编号:
分子量:
374.84
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
217-890-3
MDL number:
Beilstein/REAXYS Number:
3922393
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产品名称

氯化四苯磷, 98%

InChI key

WAGFXJQAIZNSEQ-UHFFFAOYSA-M

InChI

1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1

SMILES string

[Cl-].c1ccc(cc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

assay

98%

form

solid

mp

272-274 °C (lit.)

Quality Level

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Application

  • 四苯基氯化膦可用于调节 CH 3NH3PbI3 薄膜在沉积过程中的结晶度,以提高钙钛矿型太阳能电池 (PSCs) 器件的性能。
  • 与有机金属阴离子络合物反应生成相应的盐。
  • 在钯催化的 Heck 反应中也可作为芳基化试剂。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tetraarylphosphonium Halides as Arylating Reagents in Pd?Catalyzed Heck and Cross?Coupling Reactions.
Hwang L K, et al.
Angewandte Chemie (International Edition in English), 44(38), 6166-6169 (2005)
Efficient Perovskite Solar Cells with Reduced Photocurrent Hysteresis through Tuned Crystallinity of Hybrid Perovskite Thin Films.
Qi J, et al.
ACS Omega, 3(6), 7069-7076 (2018)
Oxoperoxo molybdenum (vi) and tungsten (vi) and oxodiperoxo molybdate (vi) and tungstate (vi) complexes with 8-quinolinol: synthesis, structure and catalytic activity.
Maiti S K, et al.
New. J. Chem., 29(4), 554-563 (2005)
M S El-Shahawi et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 27(7), 757-757 (2011-07-13)
Fast and selective sorptions of Cr(VI) species from aqueous media onto tetraphenylphosphonium bromide (TPP(+) · Br(-)) physically immobilized polyurethane foams (PUFs) sorbent were achieved. Based on the Scatchard model of binding sites of the PUFs and Langmuir and Dubinin-Radushkevich (D-R)
Jae Sung Lee et al.
The Journal of neuroscience : the official journal of the Society for Neuroscience, 28(32), 7945-7953 (2008-08-08)
At the immature calyx of Held, the fast decay phase of a Ca(2+) transient induced by tetanic stimulation (TS) was followed by a period of elevated [Ca(2+)](i) for tens of seconds, referred to as posttetanic residual calcium (Ca(res)). We investigated

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