218324
(+)-氧化柠檬烯（顺反异构体混合物）
97%
别名:
(3R)-6-甲基-3-丙-1-烯-2-基-7-氧杂双环[4.1.0]庚烷, (4R)-1-甲基-4-(1-甲基乙烯基)-7-氧杂双环[4.1.0]庚烷, (4R)-柠檬烯 1,2-环氧化物
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关于此项目
经验公式（希尔记法）:
C10H16O
化学文摘社编号:
分子量:
152.23
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(+)-氧化柠檬烯（顺反异构体混合物）, 97%
InChI
1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9?,10?/m1/s1
SMILES string
CC(=C)[C@@H]1CCC2(C)OC2C1
InChI key
CCEFMUBVSUDRLG-XNWIYYODSA-N
assay
97%
form
liquid
optical purity
ee: 98% (GLC)
refractive index
n20/D 1.466 (lit.)
bp
113-114 °C/50 mmHg (lit.)
density
0.929 g/mL at 25 °C (lit.)
functional group
ether
Quality Level
General description
氧化柠檬烯，又称为柠檬烯1,2-环氧化物，是可通过柠檬烯制备的单萜烯类物质。它具有镇痛和抗肿瘤活性，用于食品添加剂、化妆品和香水等多种产品。
Application
(+)-柠檬烯氧化物（ 顺式 和 反式 的混合物）在环氧化物水解酶存在下进行生物催化拆分，形成对映体纯的 顺式 -和 反式 -柠檬烯氧化物。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
Efficient Epoxide Hydrolase Catalyzed Resolutions of (+)-and (-)-cis/trans-Limonene Oxides.
Ferrandi EE, et al.
ChemCatChem, 7(19), 3171-3178 (2015)
Antonia Amanda C de Almeida et al.
Brain research, 1448, 56-62 (2012-03-01)
The aim of the study is to determine the acute toxicity and anxiolytic-like effects of a mixture of cis and trans of (+)-limonene epoxide in animal models of anxiety. After acute treatment with (+)-limonene epoxide at doses of 25, 50
Kelli L Hvorecny et al.
Structure (London, England : 1993), 25(5), 697-707 (2017-04-11)
Pseudomonas aeruginosa secretes an epoxide hydrolase with catalytic activity that triggers degradation of the cystic fibrosis transmembrane conductance regulator (CFTR) and perturbs other host defense networks. Targets of this CFTR inhibitory factor (Cif) are largely unknown, but include an epoxy-fatty
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