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Merck
CN

217050

Sigma-Aldrich

2-甲氧基-1,3-二氧戊环

99%

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About This Item

经验公式(希尔记法):
C4H8O3
CAS号:
分子量:
104.10
Beilstein:
103177
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

方案

99%

表单

liquid

折射率

n20/D 1.409 (lit.)

沸点

129-130 °C (lit.)

密度

1.092 g/mL at 25 °C (lit.)

官能团

ether

SMILES字符串

COC1OCCO1

InChI

1S/C4H8O3/c1-5-4-6-2-3-7-4/h4H,2-3H2,1H3

InChI key

VRAYTNFBRROPJU-UHFFFAOYSA-N

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应用

2-Methoxy-1,3-dioxolane was used in the synthesis of :
  • [4,5-bis(hydroxymethyl)-1,3-dioxolan-2-yl]nucleosides, potential inhibitors of HIV
  • diastereoisomeric cyclic acetals

象形图

Flame

警示用语:

Warning

危险声明

危险分类

Flam. Liq. 3

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

93.2 °F - closed cup

闪点(°C)

34 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of highly substituted 2, 6-anti-configured tetrahydropyrans. First steps towards an efficient access to amphidinol 3 ring system.
Dubost C, et al.
Tetrahedron Letters, 46(23), 4005-4009 (2005)
Jonas Brånalt et al.
The Journal of organic chemistry, 61(11), 3599-3603 (1996-05-31)
The synthesis of 1,3-dioxolan-2-ylnucleosides and related chemistry is described. We have shown that 2-methoxy-1,3-dioxolane (6) reacts with silylated thymine and trimethylsilyl triflate to give the acyclic formate ester 1-[2-(formyloxy)ethyl]thymine (8) rather than 1-(1,3-dioxolan-2-yl)thymine (7). A tentative mechanism which could explain

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