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方案
99%
表单
solid
mp
194-197 °C (lit.)
官能团
disulfide
nitro
SMILES字符串
[O-][N+](=O)c1ccccc1SSc2ccccc2[N+]([O-])=O
InChI
1S/C12H8N2O4S2/c15-13(16)9-5-1-3-7-11(9)19-20-12-8-4-2-6-10(12)14(17)18/h1-8H
InChI key
NXCKJENHTITELM-UHFFFAOYSA-N
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一般描述
PVC membrane electrode based on bis(2-nitrophenyl)disulfide carrier acts as sensor for zinc ions. Bis(2-nitrophenyl) disulphide undergoes mechanochemical grinding with bis(4-chlorophenyl)disulfide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene catalyst via metathesis reaction to yield non-symmetrical heterodimer 4-chlorophenyl-2′-nitrophenyl disulfide.
储存分类代码
4.1A - Other explosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
M B Gholivand et al.
Talanta, 59(2), 399-407 (2008-10-31)
A PVC membrane electrode based on bis(2-nitrophenyl)disulfide carrier exhibits a very good response for Zn(2+) in a wide concentration range (from 2.9x10(-7) to 3.2x10(-2) mol l(-1)) with a slope of 29.9+/-0.4 mV per decade of Zn(2+) concentration. The response time
Tomislav Friščić
Chemical Society reviews, 41(9), 3493-3510 (2012-03-01)
Mechanochemical reactions effected by milling or grinding are an attractive means to conduct chemical reactions dependent on molecular recognition and to systematically explore different modes of molecular self-assembly. The natural relationship between milling mechanochemistry and supramolecular chemistry arises primarily from
Szymon Sobczak et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(35), 8769-8773 (2018-04-21)
This work describes, for the first time, the application of combined pressure and temperature stimuli in disulfide metathesis reactions. In the system studied, above a pressure of 0.2 GPa, equimolar amounts of symmetric disulfides bis 4-chlorophenyl disulfide [(4-ClPhS)2 ] and bis
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