质量水平
检测方案
95%
折射率
n20/D 1.474 (lit.)
bp
58 °C/13 mmHg (lit.)
密度
0.87 g/mL at 25 °C (lit.)
SMILES字符串
CC1C(C)=C(C)C(C)=C1C
InChI
1S/C10H16/c1-6-7(2)9(4)10(5)8(6)3/h6H,1-5H3
InChI key
WQIQNKQYEUMPBM-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
研究了顺磁性内层金属富勒烯与 1，2，3，4，5-五甲基环戊二烯的 Diels-Alder 反应机理。报道了 1，2，3，4，5-五甲基环戊二烯的三步法大规模合成。用激光烧蚀质谱法研究了 1，2，3，4，5-五甲基环戊二烯 (HCp*) 在气相中与钯离子的反应。它与富含电子的烯烃发生自由基阳离子催化的环加成反应，生成 Diels-Alder 产物。
应用
1,2,3,4,5-五甲基环戊二烯用作：
- 五羰基铁中的金属有机溶剂蒸汽沉积中的生长调节剂化学品。
- 通过肟的中间体将醇催化转化为酰胺的“一锅法”铱中的配体。
- 合成[Cp*Rh(bpy)H2O]2+（Cp* = 五甲基环戊二烯基，bpy = 2,2′-联吡啶），它是 NADH 再生过程中的电子介质。
An improved synthesis of 1,2,3,4,5-pentamethylcyclopentadiene.
Kohl FX and Jutzi P.
Journal of Organometallic Chemistry, 243(1), 119-121 (1983)
Nathan A Owston et al.
Organic letters, 9(1), 73-75 (2006-12-29)
[reaction: see text] The iridium catalyst [Ir(Cp*)Cl2]2 is effective for the rearrangement of oximes to furnish amides. The reaction has been combined with catalytic transfer hydrogenation between an alcohol and alkene to allow the conversion of alcohols into amides in
The Aminium Salt and Photoinduced Electron Transfer Initiated Diels-Alder Cycloaddition of Electron-rich Allenes: Evidence for a Stepwise Mechanism and the Importance of Steric and Electronic Effects for the Reactivity of Distonic Radical Cation Intermediates.
Schmittel M, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 2(8), 1031-1040 (1996)
Journal of Organometallic Chemistry, 472, 359-359 (1994)
The use of 1, 2, 3, 4, 5 pentamethylcyclopentadiene as an in situ growth modifier chemical for the chemical vapour deposition of iron from iron pentacarbonyl.
Lane PA and Wright PJ.
Journal of Crystal Growth, 204(3), 298-301 (1999)
商品
The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. It is also referred to as a cycloaddition.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门