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Merck
CN

213853

Sigma-Aldrich

α-乙酰氨基肉桂酸

98%

别名:

N-乙酰基脱氢苯丙氨酸

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About This Item

线性分子式:
C6H5CH=C(NHCOCH3)COOH
CAS号:
分子量:
205.21
Beilstein:
1912549
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

方案

98%

mp

188-190 °C (lit.)

溶解性

methanol: soluble 100 mg/mL, clear, yellow-green
95% ethanol: soluble 5%, clear, yellow

SMILES字符串

CC(=O)N\C(=C/c1ccccc1)C(O)=O

InChI

1S/C11H11NO3/c1-8(13)12-10(11(14)15)7-9-5-3-2-4-6-9/h2-7H,1H3,(H,12,13)(H,14,15)/b10-7-

InChI key

XODAOBAZOQSFDS-YFHOEESVSA-N

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一般描述

Asymmeteric hydrogenation of α-acetamidocinnamic acid with chiral rhodium (I) complexes on charcoal has been reported. α-Acetamidocinnamic acid undergoes asymmetric hydrogenation in ionic liquid catalyzed by rhodium complex to yield (S)-phenylalanine.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Asymmetric hydrogenation of a-acetamidocinnamic acid with chiral rhodium complexes of DIOP and BPPM on charcoal.
Masami I, et al.
Chemical & Pharmaceutical Bulletin, 31(10), 3371-3376 (1983)
Choong Eui Song
Chemical communications (Cambridge, England), 9(9), 1033-1043 (2004-04-30)
Recent developments in the enantioselective chemo- and bio-catalysis in ionic liquids are reviewed. In many cases, the use of ionic liquids provides many advantages over reactions in conventional organic solvents in terms of activity, enantioselectivity, stability and the reusability of

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