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表单
liquid
质量水平
浓度
1.0 M in hexanes
密度
0.711 g/mL at 25 °C
SMILES字符串
CC[Al](Cl)CC
InChI
1S/2C2H5.Al.ClH/c2*1-2;;/h2*1H2,2H3;;1H/q;;+1;/p-1
InChI key
YNLAOSYQHBDIKW-UHFFFAOYSA-M
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应用
Diethylaluminum chloride solution can be used:
- As a Lewis acid for the synthesis of Lewis acid-base bifunctional asymmetric catalysts for cyanosilylation of aldehydes and in Strecker reaction.
- For the synthesis of precursors for lanthanide/aluminum catalysts for diene polymerization.
- As a co-initiator in the cationic polymerization of isobutylene.
包装
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Central nervous system
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
-7.6 °F
闪点(°C)
-22 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Lanthanide carboxylate precursors for diene polymerization catalysis: Syntheses, structures, and reactivity with Et2AlCl.
Organometallics, 20(26), 5751-5758 (2001)
Synthesis of new graft copolymers by combining the DPE technique and cationic polymerization.
Macromolecular Rapid Communications, 23(14), 809-813 (2002)
A Catalytic asymmetric Strecker-Type Reaction Promoted by Lewis Acid-Lewis Base Bifunctional Catalvst.
Chemical & Pharmaceutical Bulletin, 48(10), 1586-1592 (2000)
Highly enantioselective cyanosilylation of aldehydes catalyzed by a Lewis acid-Lewis base bifunctional catalyst.
Tetrahedron, 57(5), 805-814 (2001)
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