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Merck
CN

212792

Sigma-Aldrich

氢化铝锂 溶液

1.0 M in diethyl ether

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别名:
LAH, 丙氨酸锂, 四氢铝酸锂
线性分子式:
LiAlH4
CAS号:
分子量:
37.95
MDL编号:
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.22

形式

liquid

质量水平

反应适用性

reagent type: reductant

浓度

1.0 M in diethyl ether

密度

0.716 g/mL at 25 °C

储存温度

2-30°C

SMILES字符串

[Li+].[AlH4-]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

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相关类别

应用

反应物或试剂用于:
  • 由油酸制备热塑性聚酯聚酰胺
  • 锂聚合物电池
  • 宝石-二氟亚甲基衍生物的加氢脱氟
  • 不对称羟醛反应
  • 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成

LAH 是许多不同还原反应的强还原剂,例如酮类与醇类的还原反应

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 1

靶器官

Respiratory system

补充剂危害

WGK

WGK 1

闪点(°F)

1.4 °F

闪点(°C)

-17 °C

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

监管及禁止进口产品

分析证书(COA)

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Diastereoselective reductive amination of aryl trifluoromethyl ketones and alpha-amino esters.
Greg Hughes et al.
Angewandte Chemie (International ed. in English), 46(11), 1839-1842 (2007-04-24)
Krishnananda Samanta et al.
Bioorganic & medicinal chemistry letters, 20(1), 283-287 (2009-11-26)
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reduction, followed by debenzylation and finally intramolecular Mitsunobu cyclization. The new benzoxazepines specifically inhibited growth
Takahisa Nakane et al.
Chemical & pharmaceutical bulletin, 50(9), 1273-1275 (2002-09-19)
Two new migrated hopane triterpenoids, viz. 4alpha-hydroxyfilican-3-one and fern-9(11)-en-12beta-ol, and olean-18-en-3-one and olean-12-en-3-one as the first example of oleanane compounds from Adiantum ferns were isolated along with many other known triterpenoids from Adiantum capillus-veneris of China and Egypt. Their structures
Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.
Jungseok Heo et al.
Angewandte Chemie (International ed. in English), 45(6), 941-944 (2005-12-31)
Seiji Takeda et al.
Journal of biomedical nanotechnology, 9(2), 303-306 (2013-05-01)
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode materials to detect oxidized LDL electrochemically. Some carbon nanotube dispersions were studied as

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