产品名称
锌, dust, <10 μm, ≥98%
SMILES string
[Zn]
InChI
1S/Zn
InChI key
HCHKCACWOHOZIP-UHFFFAOYSA-N
vapor pressure
1 mmHg ( 487 °C)
assay
≥98%
form
dust
reaction suitability
core: zinc
reagent type: catalyst
resistivity
5.8 μΩ-cm, 20°C
particle size
<10 μm
bp
907 °C (lit.)
mp
420 °C (lit.)
density
7.133 g/mL at 25 °C (lit.)
Quality Level
Application
还原剂；用于制备有机锌试剂、Reformatsky 试剂和 Simmons-Smith 试剂（环丙烷化）。
锌也用作：
锌也用作：
- 间歇反应器中水热 CO2 还原为甲酸的还原剂。
- 乙腈中醛、胺和炔烃一锅三组分偶联合成炔丙基胺的催化剂。
General description
锌是有机反应中一种廉价、易得的通用试剂，通常用作有机合成中的还原剂。锌粉用于还原羰基、卤化碳键、碳氧键、炔烃和杂原子键，如 N-N 和 N-O 键。它还用于制备各种有机锌试剂。 此外，锌已经被用于一些众所周知的命名反应中，如 Reformatsky 反应、Knorr 吡咯合成、Serini 反应和 Simmons-Smith 环丙烷化。
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
法规信息
监管及禁止进口产品
此项目有
Nicholas A Isley et al.
Green chemistry : an international journal and green chemistry resource : GC, 2015, 307-307 (2014-12-23)
Alkyl bromides and chlorides can be reduced to the corresponding hydrocarbons utilizing zinc in the presence of an amine additive. The process takes place in water at ambient temperatures, enabled by a commercially available designer surfactant. The reaction medium can
Activated zinc dust
Smith CR
Synlett, 2009(09), 1522-1523 (2009)
Efficient one-pot synthesis of propargylamines using zinc dust
Kantam ML, et al.
Tetrahedron Letters, 48(41), 7332-7334 (2007)
Knochel, P.
Chemical Reviews, 93, 217-217 (1993)
Sara Eyal et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 50(5), 798-806 (2009-05-01)
Studies in rodents indicate that the disruption of P-glycoprotein (P-gp) function increases drug distribution into the developing fetus and organs such as the brain. To simultaneously and serially evaluate the effect of P-gp activity and inhibition on the tissue distribution
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