所有图片(2)
别名:
二羰基氯化铑, 二羰基氯铑二聚体, 四羰基-μ-氯二铑(I), 氯化二羰酰铑
线性分子式:
[Rh(CO)2Cl]2
CAS号:
分子量:
388.76
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
检测方案
97%
形式
powder
反应适用性
core: rhodium
reagent type: catalyst
mp
120-125 °C (dec.) (lit.)
储存温度
2-8°C
SMILES字符串
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Cl+]1[Rh-][Cl+][Rh-]1
InChI
1S/4CO.2Cl.2Rh/c4*1-2;;;;/q;;;;2*+1;2*-1
InChI key
ODYPMWFHWPMOKS-UHFFFAOYSA-N
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一般描述
二-μ-氯-四羰基二铑（I）可作为催化剂或催化剂前体用于各种有机反应，比如Pauson-Khand反应、烯丙基烷基化、张力环重排、羰基化扩环、有机金属羰基偶联、加氢甲酰化、甲硅烷甲酰化和烯烃、炔烃、丙二烯的环加成反应。
应用
- Rhodium-Catalyzed Trans-Bis-Silylation Reactions: This study explores the use of Di-μ-chloro-tetracarbonyldirhodium(I) as a catalyst in the synthesis of specialized pyridine derivatives, demonstrating potential for creating complex molecular architectures useful in drug discovery and material science (Naka & Kobayashi, 2023).
- Redox behaviour of imino-β-diketonato ligands: The research investigates the coordination chemistry of Di-μ-chloro-tetracarbonyldirhodium(I) with innovative ligands, potentially opening new pathways for catalytic systems used in pharmaceutical syntheses (Ferreira, Conradie & Conradie, 2022).
- Synthesis of Thiophene-Fused Siloles through Rhodium-Catalyzed Trans-Bis-Silylation: The application of Di-μ-chloro-tetracarbonyldirhodium(I) in the synthesis of thiophene-fused siloles indicates its role in advancing materials chemistry for electronic and photonic applications (Naka et al., 2024).
- Kinetic Study of the Oxidative Addition Reaction between Methyl Iodide and Complexes: Utilizing UV–Vis, IR spectroscopy, this study enhances understanding of the mechanisms involved when using Di-μ-chloro-tetracarbonyldirhodium(I) in catalytic cycles, relevant to both academia and industry settings (Ferreira et al., 2022).
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
The Journal of Organic Chemistry, 58, 4187-4187 (1993)
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