208795
甲基硫代磺酸甲酯
97%
别名:
S-甲基硫代甲基砜, MMTS
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线性分子式:
CH3SO2SCH3
化学文摘社编号:
分子量:
126.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-970-0
Beilstein/REAXYS Number:
1446059
MDL number:
Assay:
97%
Form:
liquid
InChI key
XYONNSVDNIRXKZ-UHFFFAOYSA-N
InChI
1S/C2H6O2S2/c1-5-6(2,3)4/h1-2H3
SMILES string
CSS(C)(=O)=O
assay
97%
form
liquid
Quality Level
refractive index
n20/D 1.513 (lit.)
bp
69-71 °C/0.4 mmHg (lit.)
solubility
DMF: soluble 1:1, chloroform: soluble 200 ul per mL, clear, faintly yellow-green, water: soluble 1:5
density
1.337 g/mL at 25 °C (lit.)
functional group
disulfide
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General description
S-甲基硫代磺酸甲酯是用于合成硫醇和硫酯的试剂。用作制备聚合物网络的交联剂。 S-甲基硫代磺酸甲酯（MMTS）与二棕榈酰磷脂酰胆碱（DPPC）双层的相互作用已经通过FTIR和表面增强拉曼光谱进行研究。
Application
S-甲基硫代磺酸甲酯被用作β-酮亚砜、亚甲基化合物、丙二酸半酯 和芳基格氏试剂的亚磺酰化试剂。它还被用作捕获天然硫醇-二硫化物形式的蛋白质的试剂。
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Skin Sens. 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
Journal of the Chemical Society. Perkin Transactions 1, 3167-3167 (1993)
Sustainable Three-Component Synthesis of Isothioureas from Isocyanides, Thiosulfonates, and Amines
P Mampuys, et al.
Angewandte Chemie (International Edition in English), 126 (2014)
Synthetic Communications, 22, 1359-1359 (1992)
Sustainable Three-Component Synthesis of Isothioureas from Isocyanides, Thiosulfonates, and Amines
P Mampuys, et al.
Angewandte Chemie (International Edition in English), 126, 13063-13068 (2014)
W H Briggs et al.
Journal of agricultural and food chemistry, 48(11), 5731-5735 (2000-11-23)
Thiosulfinates (TSs) have been implicated as a principle source of the antiplatelet property of raw onion and garlic juice. The in vitro responses of human platelets to dosages of four TSs were measured using whole blood aggregometry and compared by
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