质量水平
方案
97%
表单
liquid
折射率
n20/D 1.513 (lit.)
沸点
69-71 °C/0.4 mmHg (lit.)
溶解性
DMF: soluble 1:1
chloroform: soluble 200 ul per mL, clear, faintly yellow-green
water: soluble 1:5
密度
1.337 g/mL at 25 °C (lit.)
官能团
disulfide
SMILES字符串
CSS(C)(=O)=O
InChI
1S/C2H6O2S2/c1-5-6(2,3)4/h1-2H3
InChI key
XYONNSVDNIRXKZ-UHFFFAOYSA-N
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一般描述
S-甲基硫代磺酸甲酯是用于合成硫醇和硫酯的试剂。用作制备聚合物网络的交联剂。 S-甲基硫代磺酸甲酯(MMTS)与二棕榈酰磷脂酰胆碱(DPPC)双层的相互作用已经通过FTIR和表面增强拉曼光谱进行研究。
应用
S-甲基硫代磺酸甲酯被用作β-酮亚砜、亚甲基化合物、丙二酸半酯 和芳基格氏试剂的亚磺酰化试剂。它还被用作捕获天然硫醇-二硫化物形式的蛋白质的试剂。
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
188.6 °F - closed cup
闪点(°C)
87 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Journal of the Chemical Society. Perkin Transactions 1, 3167-3167 (1993)
Sustainable Three-Component Synthesis of Isothioureas from Isocyanides, Thiosulfonates, and Amines
P Mampuys, et al.
Angewandte Chemie (International Edition in English), 126 (2014)
Synthetic Communications, 22, 1359-1359 (1992)
W H Briggs et al.
Journal of agricultural and food chemistry, 48(11), 5731-5735 (2000-11-23)
Thiosulfinates (TSs) have been implicated as a principle source of the antiplatelet property of raw onion and garlic juice. The in vitro responses of human platelets to dosages of four TSs were measured using whole blood aggregometry and compared by
Anna-Riikka Karala et al.
Antioxidants & redox signaling, 9(4), 527-531 (2007-02-07)
S-Methyl methanethiosulfonate (MMTS) is a reagent used to trap the natural thiol-disulfide state of the proteins. The efficiency of trapping mixed disulfides in vivo has been found to be higher for MMTS than for the more commonly used N-ethylmaleimide. MMTS
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