208264
烯丙基三甲基硅烷
98%
别名:
3-(三甲基硅基)丙烯
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关于此项目
线性分子式:
H2C=CHCH2Si(CH3)3
化学文摘社编号:
分子量:
114.26
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-104-5
Beilstein/REAXYS Number:
906755
MDL number:
InChI key
HYWCXWRMUZYRPH-UHFFFAOYSA-N
InChI
1S/C6H14Si/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3
SMILES string
C[Si](C)(C)CC=C
assay
98%
form
liquid
Quality Level
refractive index
n20/D 1.407 (lit.)
bp
84-88 °C (lit.)
density
0.719 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Application
烯丙基三甲基硅烷是一种将烯丙基引入氯化酰基、醛类、酮类、亚胺离子、烯酮类以及与其他碳亲电试剂交叉偶联的通用试剂。它被用作Hosomi−Sakurai反应中的试剂。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Ionic liquid-promoted, highly regioselective heck arylation of electron-rich olefins by aryl halides
Mo J, et al.
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Organic letters, 5(24), 4639-4640 (2003-11-25)
[reaction: see text] Direct allylation of glycal-derived donor-acceptor cyclopropanes has been achieved with TiCl(4) activation followed by addition of allyltrimethylsilane. The alpha diastereomer is the major product, with selectivities ranging from 3:1 to 10:1 and yields around 80%.
Control of alpha/beta stereoselectivity in Lewis acid promoted C-glycosidations using a controlling anomeric effect based on the conformational restriction strategy.
Satoru Tamura et al.
Angewandte Chemie (International ed. in English), 42(9), 1021-1023 (2003-03-05)
A general and efficient FeCl3-catalyzed nucleophilic substitution of propargylic alcohols
Zhan Z, et al.
The Journal of Organic Chemistry, 71(21), 8298-8301 (2006)
Roman Schowner et al.
Angewandte Chemie (International ed. in English), 59(2), 951-958 (2019-11-28)
The origin of hydroxyl group tolerance in neutral and especially cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes has been investigated. A wide range of catalysts was prepared and tested. Most cationic complexes can be handled in air without difficulty
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