206113
氯化铂(IV)
96%
别名:
四氯化铂
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关于此项目
线性分子式:
PtCl4
化学文摘社编号:
分子量:
336.89
PubChem Substance ID:
eCl@ss:
38191307
UNSPSC Code:
12352302
NACRES:
NA.23
EC Number:
236-645-1
MDL number:
Assay:
96%
Form:
powder and chunks
InChI key
FBEIPJNQGITEBL-UHFFFAOYSA-J
InChI
1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Pt](Cl)(Cl)Cl
assay
96%
form
powder and chunks
reaction suitability
core: platinum, reagent type: catalyst
mp
370 °C (dec.) (lit.)
density
4.303 g/mL at 25 °C (lit.)
application(s)
PEM fuel cells
homogeneous catalyst
material synthesis precursor
Quality Level
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Application
氯化铂(IV) 可作为前体用于合成各种有机转化反应中的铂基催化剂。例如，碳载铂-钌纳米颗粒可用作甲醇和乙醇氧化的高效催化剂。
由于其对糖基受体羟基的高亲和力和双齿配体结合能力，它可用作区域和立体选择性糖苷化反应的双功能催化剂。
它也可用于TiO2 的光敏化和表面修饰，从而实现4-氯苯酚的光降解。
由于其对糖基受体羟基的高亲和力和双齿配体结合能力，它可用作区域和立体选择性糖苷化反应的双功能催化剂。
它也可用于TiO2 的光敏化和表面修饰，从而实现4-氯苯酚的光降解。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
A M Reichlmayr-Lais et al.
Journal of trace elements and electrolytes in health and disease, 6(3), 183-187 (1992-09-01)
In experiments with rats dose-response relationships of alimentary PtCl2 and PtCl4 were investigated. 2 x 81 animals weighing 35 g were randomly distributed among 9 treatment groups which were fed ad libitum with a synthetic diet containing various amounts of
Eric Ennifar et al.
Nucleic acids research, 31(10), 2671-2682 (2003-05-09)
Metal ions, and magnesium in particular, are known to be involved in RNA folding by stabilizing secondary and tertiary structures, and, as cofactors, in RNA enzymatic activity. We have conducted a systematic crystallographic analysis of cation binding to the duplex
Ivana Bednarova et al.
Neuro endocrinology letters, 33 Suppl 3, 107-112 (2013-01-29)
An enhanced worldwide application of platinum group elements (PGE), in particular platinum, has been observed during recent decades. An increased concentration of PGE was determined in collected samples of great amount of aqueous ecosystems.The aim was to compare phytotoxic effect
A P Boswell et al.
The Biochemical journal, 201(3), 523-526 (1982-03-01)
The binding of [PtCl4]2- and cis-[PtCl2(NH3)2] to methionine-65 of tuna cytochrome c was investigated by 1H n.m.r. The modification at methionine-65 is shown to cause an extremely small structural perturbation to the protein at the site of modification.
Jochen Autschbach et al.
Magnetic resonance in chemistry : MRC, 46 Suppl 1, S45-S55 (2008-10-16)
Pt chemical shifts were calculated from two-component relativistic density functional theory (DFT). The shielding tensors were analyzed by using a recently developed method to decompose the spin-orbit DFT results into contributions from spin-free localized orbitals (here: natural localized molecular orbitals
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