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Merck
CN

206113

Sigma-Aldrich

氯化铂(IV)

96%

别名:

四氯化铂

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About This Item

线性分子式:
PtCl4
CAS号:
分子量:
336.89
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38191307
PubChem化学物质编号:
NACRES:
NA.23
方案:
96%
表单:
powder and chunks

质量水平

方案

96%

表单

powder and chunks

反应适用性

reagent type: catalyst
core: platinum

mp

370 °C (dec.) (lit.)

密度

4.303 g/mL at 25 °C (lit.)

SMILES字符串

Cl[Pt](Cl)(Cl)Cl

InChI

1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4

InChI key

FBEIPJNQGITEBL-UHFFFAOYSA-J

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应用

氯化铂(IV) 可作为前体用于合成各种有机转化反应中的铂基催化剂。例如,碳载铂-钌纳米颗粒可用作甲醇和乙醇氧化的高效催化剂。

由于其对糖基受体羟基的高亲和力和双齿配体结合能力,它可用作区域和立体选择性糖苷化反应的双功能催化剂。

它也可用于TiO2 的光敏化和表面修饰,从而实现4-氯苯酚的光降解。

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ivana Bednarova et al.
Neuro endocrinology letters, 33 Suppl 3, 107-112 (2013-01-29)
An enhanced worldwide application of platinum group elements (PGE), in particular platinum, has been observed during recent decades. An increased concentration of PGE was determined in collected samples of great amount of aqueous ecosystems.The aim was to compare phytotoxic effect
Lu Zhao et al.
Zhejiang da xue xue bao. Yi xue ban = Journal of Zhejiang University. Medical sciences, 38(1), 59-66 (2009-03-03)
To construct a drug carrier and gene vector PEG-PEI-Pt. Polyethyleneglycol (PEG) was coupled to polyethylenimine (PEI 600) and platinum tetrachloride; PEG-PEI-Pt complex was formed in ethanol. The complex was characterized by XRD, UV-VIS and FT-IR and the DNA condensation was
N Kanematsu et al.
Gifu Shika Gakkai zasshi = The Journal of Gifu Dental Society, 17(2), 575-581 (1990-12-01)
The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (HGPRT) locus in V-79 cells. Cadmium chloride at a concentration of 0.05 microM induced ford mutation in V-79
Jochen Autschbach et al.
Magnetic resonance in chemistry : MRC, 46 Suppl 1, S45-S55 (2008-10-16)
Pt chemical shifts were calculated from two-component relativistic density functional theory (DFT). The shielding tensors were analyzed by using a recently developed method to decompose the spin-orbit DFT results into contributions from spin-free localized orbitals (here: natural localized molecular orbitals
A P Boswell et al.
The Biochemical journal, 201(3), 523-526 (1982-03-01)
The binding of [PtCl4]2- and cis-[PtCl2(NH3)2] to methionine-65 of tuna cytochrome c was investigated by 1H n.m.r. The modification at methionine-65 is shown to cause an extremely small structural perturbation to the protein at the site of modification.

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