所有图片(2)
别名:
四氯化铂
线性分子式:
PtCl4
CAS号:
分子量:
336.89
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38191307
PubChem化学物质编号:
NACRES:
NA.23
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质量水平
检测方案
96%
形式
powder and chunks
反应适用性
reagent type: catalyst
core: platinum
mp
370 °C (dec.) (lit.)
密度
4.303 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Pt](Cl)(Cl)Cl
InChI
1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4
InChI key
FBEIPJNQGITEBL-UHFFFAOYSA-J
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应用
氯化铂(IV) 可作为前体用于合成各种有机转化反应中的铂基催化剂。例如，碳载铂-钌纳米颗粒可用作甲醇和乙醇氧化的高效催化剂。
由于其对糖基受体羟基的高亲和力和双齿配体结合能力，它可用作区域和立体选择性糖苷化反应的双功能催化剂。
它也可用于TiO2 的光敏化和表面修饰，从而实现4-氯苯酚的光降解。
由于其对糖基受体羟基的高亲和力和双齿配体结合能力，它可用作区域和立体选择性糖苷化反应的双功能催化剂。
它也可用于TiO2 的光敏化和表面修饰，从而实现4-氯苯酚的光降解。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Ivana Bednarova et al.
Neuro endocrinology letters, 33 Suppl 3, 107-112 (2013-01-29)
An enhanced worldwide application of platinum group elements (PGE), in particular platinum, has been observed during recent decades. An increased concentration of PGE was determined in collected samples of great amount of aqueous ecosystems.The aim was to compare phytotoxic effect
Lu Zhao et al.
Zhejiang da xue xue bao. Yi xue ban = Journal of Zhejiang University. Medical sciences, 38(1), 59-66 (2009-03-03)
To construct a drug carrier and gene vector PEG-PEI-Pt. Polyethyleneglycol (PEG) was coupled to polyethylenimine (PEI 600) and platinum tetrachloride; PEG-PEI-Pt complex was formed in ethanol. The complex was characterized by XRD, UV-VIS and FT-IR and the DNA condensation was
Barbora Nemcova et al.
Neuro endocrinology letters, 33 Suppl 3, 173-178 (2013-01-29)
Regarding the environmental pollution, platinum group elements (PGE) are in the centre of interest of current research. These rare elements are used as effective substances in automotive catalysts to reduce pollution by emissions originating from fuel combustion. Due to their
PtCl4-catalyzed domino synthesis of fused bicyclic acetals.
Alejandro Diéguez-Vázquez et al.
Angewandte Chemie (International ed. in English), 47(1), 209-212 (2007-12-07)
Agnieszka Jańczyk et al.
Journal of photochemistry and photobiology. B, Biology, 92(1), 54-58 (2008-06-17)
Phototoxicity of titanium dioxide modified with platinum(IV)-chloride complexes, [TiO2/PtCl4], irradiated with visible light was tested on murine macrophage cell line (RAW 264.7) in vitro. Presence of antioxidants such as alpha-tocopherol or beta-carotene during photodynamic treatment significantly increased cells viability. Our
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