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Merck
CN

205699

Sigma-Aldrich

碳负载钯催化剂

greener alternative

extent of labeling: 10 wt. % loading, matrix activated carbon support

别名:

Pd/C

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About This Item

线性分子式:
Pd
分子量:
106.42
MDL编号:
UNSPSC代码:
12141733
eCl@ss:
38191001
PubChem化学物质编号:
NACRES:
NA.22

形式

powder

质量水平

反应适用性

core: palladium
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

标记范围

10 wt. % loading

基质

activated carbon support

环保替代产品分类

SMILES字符串

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了能源效率。点击此处,查看更多详情。

应用

催化以下反应:
  • Stille反应
  • 氢化反应
  • Suzuki-Miyaura交叉偶联反应和Heck-Mizoroki反应
  • 脱氧反应
  • 氧化反应
  • 偶联反应
钯碳(Pd/C)(10 wt.%载量,活性碳载体)可用作许多熟知反应的催化剂,例如烯烃、炔烃、酮、腈、亚胺、叠氮化物、硝基、苯类和杂环芳烃的氢化反应,环丙烷、苄基衍生物、环氧化物、肼和卤化物的氢解反应,芳基化合物脱氢反应和醛脱甲酰反应。
也用于:

  • 作为催化剂参与温室气体二氯二氟甲烷(CCl2F2))的加氢脱氯
  • 作为催化剂参与离子液中芳基卤化物的Heck反应
  • 作为阳极催化剂制造直接甲酸燃料电池 (DFAFC)
  • 作为高性价比的电催化剂用于甲醇的氧化
  • 用于氢化物的催化加氢以生产氢气
  • 作为Suzuki-Mayaura反应催化剂
产品适配我们的台式制氢仪:H-Genie Lite (Z744083)

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ (Lot或Batch)字后找到。

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How does product number 205699, Palladium on Carbon, differ from 330108, which is also 10 wt % palladium on activated carbon?

    Product number 330108 is the wet support and appears as a moist black powder.  Product number 205699 is dry.

  4. Is Product 205699, Palladium on carbon, reduced or unreduced?

    It is reduced, but it can oxidize pretty readily.

  5. What is the particle size of Product 205699, Palladium on carbon?

    We expect the product to conform to the following: approximately 90% <60 μm and 10% <5 μm with an average particle size of 15 μm. 

  6. What is the activity of Product 205699, Palladium on carbon?  How is the activity tested?  Is it a guaranteed value?

    There is a fairly large variance in activity reported by the manufacturer on this material (from less than 50 ml/min to more than 100 ml/min).  Activity is not a specification but reported on the Certification of Analysis for further information.  Activity is measured by the hydrogen reduction of nitrobenzene. 

  7. What is the surface area of Product 205699, Palladium on carbon?

    The surface area of the carbon used as the support is 750-1000 m2 /g.  They do not test the surface area of the finished catalyst.

  8. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  9. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  10. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Characterisation of the deactivation of platinum and palladium supported on activated carbon used as hydrodechlorination catalysts
Ordonez S, et al.
Applied Catalysis. B, Environmental, 31(2), 113-122 (2001)
Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid
Hagiwara H, et al.
Tetrahedron Letters, 42(26), 4349-4351 (2001)
Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride
Patel N, et al.
International Journal of Hydrogen Energy, 33(1), 287-292 (2008)
Pd/C: an old catalyst for new applications-its use for the Suzuki-Miyaura reaction
Felpin F, et al.
European Journal of Organic Chemistry, 2006(12), 2679-2690 (2006)
Physical and electrochemical characterizations of nanostructured Pd/C and PdNi/C catalysts for methanol oxidation
Liu Z, et al.
Electrochemical Communications, 11(4), 925-928 (2009)

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