product name
二碳酸二叔丁酯, ReagentPlus®, 99%
质量水平
产品线
ReagentPlus®
检测方案
99%
形式
solid or liquid
折射率
n20/D 1.409 (lit.)
bp
56-57 °C/0.5 mmHg (lit.)
mp
23 °C (lit.)
密度
0.95 g/mL at 25 °C (lit.)
应用
peptide synthesis
储存温度
2-8°C
SMILES字符串
CC(C)(C)OC(=O)OC(=O)OC(C)(C)C
InChI
1S/C10H18O5/c1-9(2,3)14-7(11)13-8(12)15-10(4,5)6/h1-6H3
InChI key
DYHSDKLCOJIUFX-UHFFFAOYSA-N
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应用
Boc保护胺制备溶剂。
Tris-Boc保护的肼可在显色试剂中制备Fmoc酯以监测固相醛。
使用Synple自动合成平台(SYNPLE-SC002)、Boc保护试剂盒((SYNPLE-B001)、(SYNPLE-B002)和Boc脱保护试剂盒(SYNPLE-B011),可自动进行Boc保护和脱保护
使用Synple自动合成平台(SYNPLE-SC002)、Boc保护试剂盒((SYNPLE-B001)、(SYNPLE-B002)和Boc脱保护试剂盒(SYNPLE-B011),可自动进行Boc保护和脱保护
用于引入Boc保护基的试剂。
通过 Lewis 酸催化作用可以保护叔丁氧羰基衍生物等醇类。
通过叔丁氧羰基氨基丙炔与甲醛、二异丙胺以及溴化铜的反应来制备氨甲基丙二烯,是许多牛血浆胺氧化酶灭活剂的组分。
警告
水解为叔丁醇和 CO2;暴露在潮湿环境中会导致瓶内压力增大。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险分类
Acute Tox. 1 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
非剧毒-急性毒性1
危险化学品
Journal of the American Chemical Society, 126(25), 8038-8045 (2004-06-24)
Propargylic and activated allylic amines are known to inactivate the quinone-dependent plasma amine oxidases, possibly through active-site modification by the alpha,beta-unsaturated aldehyde turnover products. Although homopropargylamine (1-amino-3-butyne, 1) is a nonobvious candidate as a mechanism-based inhibitor, 1 was found to
The Journal of organic chemistry, 69(14), 4586-4594 (2004-07-03)
A direct method for quantifying solid-phase aldehydes has been developed, using a new reagent, 4-(9-fluorenylmethyloxycarbonyl)phenylhydrazine (FmPH). The FmPH reagent was synthesized in three steps (24% overall yield) from commercially available p-hydrazinobenzoic acid. Resin-bound aldehydes reacted quantitatively with FmPH, in the
Synthetic Communications, 23, 1443-1443 (1993)
Synlett, 2104-2104 (2006)
Angewandte Chemie (International ed. in English), 53(44), 11766-11771 (2014-09-10)
Carbonic acid (H2CO3), an essential molecule of life (e.g., as bicarbonate buffer), has been well characterized in solution and in the solid state, but for a long time, it has eluded its spectral characterization in the gas phase owing to
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