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质量水平
方案
99.99% trace metals basis
表单
solid
反应适用性
core: thallium
reagent type: catalyst
mp
632 °C (lit.)
密度
6.77 g/mL at 25 °C (lit.)
SMILES字符串
[Tl+].[Tl+].[O-]S([O-])(=O)=O
InChI
1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2
InChI key
YTQVHRVITVLIRD-UHFFFAOYSA-L
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一般描述
Thallium(I) sulfate is mainly used in organic synthesis as an oxidizing agent. It can facilitate the oxidation of various organic compounds, such as alcohols, to corresponding aldehydes or ketones. This reaction is commonly known as the Reformatsky reaction.1 Additionally, thallium sulfate is employed in the preparation of thallium salts for use in analytical chemistry and research applications. It is also utilized in the production of luminous paints, photoelectric cells, and low-melting glasses.
应用
Thallium(I)sulfate is also utilized in:
- the synthesis of alkylated cyclopentadienes and 7-substitutedbicyclo[2.2.1]heptane derivatives
- inthe preparation of thallium borate species such as TlBPH43
警示用语：
Danger
危险分类
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Irrit. 2 - STOT RE 1 Oral
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
Methoxymethylation of thallous cyclopentadienide. Simplified preparation of a key intermediate for the synthesis of prostaglandins
Elias J. Corey, Urs Koelliker, and Jorg Neuffer
Journal of the American Chemical Society, 93(6), 1489?1490-1489?1490 (1971)
J P Mulkey et al.
Veterinary and human toxicology, 40(1), 11-14 (1998-02-19)
Thallium is a highly toxic cumulative poison in humans and animals. The use of the metal as a component in ceramic superconductor material (CSM) raised concern about the health risk of CSM to children accidentally swallowing some of the CSM
The pollen tube growth test.
U Kristen et al.
Methods in molecular biology (Clifton, N.J.), 43, 189-198 (1995-01-01)
D Appenroth et al.
Toxicology letters, 122(3), 255-265 (2001-08-08)
Antioxidants of the vitamin E family have protective effects against metal toxicity. We examined the protective effect of racemic LLU-alpha [2,7,8-trimethyl-2-(carboxyethyl)-6-hydroxychroman] a metabolite of gamma-tocopherol, in comparison to the effect of alpha- and gamma-tocopherol in rats treated with sodium dichromate
Changes in adenosine triphosphate (ATP) concentration and its activity in murine tissue after thallium administration.
M Yoshida et al.
Bulletin of environmental contamination and toxicology, 59(2), 268-273 (1997-08-01)
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