202304
聚(丙二醇)
average Mn ~425
别名:
PPG, 聚环氧丙烷
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线性分子式:
H[OCH(CH3)CH2]nOH
化学文摘社编号:
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
Bp:
287.6 °C
Vapor pressure:
<0.01 mmHg ( 20 °C)
InChI key
DUFKCOQISQKSAV-UHFFFAOYSA-N
SMILES string
CC(O)CO
InChI
1S/C6H14O3/c1-5(8)4-9-6(2)3-7/h5-8H,3-4H2,1-2H3
vapor density
>1 (vs air)
vapor pressure
<0.01 mmHg ( 20 °C)
mol wt
average Mn ~425
contains
130-190 ppm proprietary phenolic antioxidant
refractive index
n20/D 1.447
viscosity
80 cSt(25 °C)(lit.)
bp
287.6 °C
hydroxyl value
263 mg KOH/g
solubility
water: miscible (completely)
density
1.004 g/mL at 25 °C
Quality Level
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Application
聚(丙二醇)可用：
- 增塑剂，因为它不结晶，具有较低的玻璃化转变温度，并具有生物相容性。例如，它可以用于聚乳酸的塑化。
- 制备从盐单胞菌细胞中回收 Ectoine 的水双相体系。
- 研究超分子聚合物（PPG）向常规聚合物（PPO）的虚拟转变。
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
445.0 °F - closed cup
flash_point_c
229.44 °C - closed cup
ppe
Eyeshields, Gloves
Flávia Chiva Carvalho et al.
Journal of biomedical nanotechnology, 8(2), 280-289 (2012-04-21)
In the last few decades, nanotechnology has led to an advance in the development of topical drug delivery. Nanostructured drug delivery systems enable the compartmentalization of drugs in restricted environments, modifying the release profile and maintaining the required drug concentration
Celeste R Brennecka et al.
World neurosurgery, 78(5), 469-480 (2011-11-29)
Current treatments for cerebral aneurysms are far from ideal. Platinum coils are prone to compaction, and currently used liquid embolics are delivered with angiotoxic agents. This work presents initial in vivo studies of a novel liquid-to-solid gelling polymer system (PPODA-QT)
John Texter et al.
Macromolecular rapid communications, 33(1), 69-74 (2011-12-03)
The controlled atom transfer radical polymerization of an ionic liquid, 1-(11-acryloylundecyl)-3-methyl imidazolium bromide (ILBr), from both ends of a telechelic poly(propylene oxide) (PPO) macroinitiator, end-functionalized with bromoisobutyryloyl is reported. The resulting highly water-soluble triblock, poly(ILBr-b-PO-b-ILBr) is multistimuli responsive. This new
Mohammed Taghi Zafarani-Moattar et al.
Biotechnology progress, 28(1), 146-156 (2011-09-29)
In this work, we proposed a novel aqueous biphasic system (ABS) composed of polypropylene glycol P400 (PPG P400) and hydrophilic ionic liquids (IL), 1-alkyl-3-methylimidazolium bromide (alkyl = ethyl or butyl), forming an upper polymer-rich phase and a lower IL-rich phase
R De Lisi et al.
Physical chemistry chemical physics : PCCP, 13(27), 12571-12577 (2011-06-15)
The study highlighted the main forces driving the formation of hydroxypropyl-cyclodextrins (HP-CDs) + poly(propylene) glycol 725 g mol(-1) inclusion complexes. The temperature parameter was chosen as the variable to modulate the hydrophobicity of the polymer, and consequently ITC experiments as
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