所有图片(1)
别名:
NSC 124140, RhCl (PPh 3 ) 3, Wilkinson 催化剂, 三(三苯膦基)氯化铑(I)
线性分子式:
[(C6H5)3P]3RhCl
CAS号:
分子量:
925.22
Beilstein:
4581440
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
反应适用性
core: rhodium
reagent type: catalyst
SMILES字符串
Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key
IXAYKDDZKIZSPV-UHFFFAOYSA-M
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一般描述
三（三苯基膦）氯化铑（I）在Heck反应中被用作脱羧试剂和协同催化剂。
应用
警示用语：
Warning
危险声明
危险分类
Aquatic Chronic 4 - Skin Sens. 1
WGK
WGK 3
个人防护装备
Eyeshields, Gloves, type N95 (US)
Palladium (II) acetate- Tris (triphenylphosphine) rhodium (I) chloride: a novel catalytic couple for the intramolecular heck reaction
Donald B
The Journal of Organic Chemistry, 64, 3461-3466 (1999)
The Journal of Organic Chemistry, 57, 5075-5075 (1992)
Stereochemistry of tris (triphenylphosphine) rhodium chloride decarbonylation of aldehydes
HM Walborsky et al.
Journal of the American Chemical Society, 93, 5465-5468 (1971)
Chemical Reviews, 91, 1179-1179 (1991)
P Andrew Evans et al.
Journal of the American Chemical Society, 124(30), 8782-8783 (2002-07-26)
Transition metal-catalyzed cycloaddition reactions represent powerful methods for the construction of complex polycyclic systems. We have developed a new intermolecular metal-catalyzed [4 + 2 + 2] cycloaddition of heteroatom-tethered enyne derivatives with 1,3-butadiene. This study demonstrates that excellent selectivity can
商品
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
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