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表单
liquid
质量
packed in FEP bottles
反应适用性
reagent type: oxidant
浓度
52.9-66.8% (iodometric)
~5.5 M in decane (over molecular sieve 4Å)
折射率
n20/D 1.403
密度
0.83 g/mL at 20 °C
储存温度
2-8°C
SMILES字符串
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
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应用
用于燃料的氧化脱硫以及作为苯乙烯环氧化的氧化剂。
其他说明
用于Sharpless环氧化的安全稳定的氧化剂
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
闪点(°F)
109.4 °F - closed cup
闪点(°C)
43 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Controlled synthesis of a- and c-Fe2O3 nanoparticles via thermolysis of PVA gels and studies on a-Fe2O3 catalyzed styrene epoxidation.
Bepari RA,et al.
Journal of Saudi Chemical Society (2014)
Oxidative desulfurization of fuel oil. Part I. Oxidation of dibenzothiphenes using tert-butyl hydroperoxide
Wang D,et al.
Applied Catalysis A: General, 253, 91-99 (2003)
K. Akashi et al.
The Journal of Organic Chemistry, 43, 2063-2063 (1978)
Maxim O Ratnikov et al.
Journal of the American Chemical Society, 135(4), 1549-1557 (2013-01-10)
A general mechanism is proposed for transition metal-catalyzed oxidative Mannich reactions of N,N-dialkylanilines with tert-butyl hydroperoxide (TBHP) as the oxidant. The mechanism consists of a rate-determining single electron transfer (SET) that is uniform from 4-methoxy- to 4-cyano-N,N-dimethylanilines. The tert-butylperoxy radical
Younghwa Kim et al.
Food chemistry, 137(1-4), 136-141 (2012-12-04)
Oligomeric and polymeric procyanidins have been reported to possess different antioxidant capacities. However, the intracellular antioxidant mechanisms of oligomeric and polymeric procyanidins are still poorly understood. In this study, we evaluated the cytoprotective effects of the oligomeric procyanidin fraction (OPF)
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