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Merck
CN

199958

Sigma-Aldrich

六羰基钼

98%

别名:

羰化钼

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About This Item

线性分子式:
Mo(CO)6
CAS号:
分子量:
264.00
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:

蒸汽密度

9.1 (vs air)

方案

98%

表单

solid

反应适用性

core: molybdenum
reagent type: catalyst

沸点

156 °C (lit.)

mp

150 °C (dec.) (lit.)

密度

1.96 g/mL at 25 °C (lit.)

SMILES字符串

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChI key

KMKBZNSIJQWHJA-UHFFFAOYSA-N

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一般描述

六羰基钼是一种白色结晶固体,在 150 ° C 下熔融,密度为 1.96 gm/cc,不溶于水和可溶在大多数有机溶剂中。

应用

用于二氧化硅的接枝,作为烯烃环氧化的催化剂, 从液体燃料中吸附有机硫化合物,作为生产有机钼染料和热分解镀钼的前体。

象形图

Skull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Inhalation

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor
Abrantes M, et al
Catalysis Communications, 15(1), 64-67 (2011)
Advanced Synthesis & Catalysis, 352(10), 1759-1769 (2010)
Selective adsorption of dibenzothiophene by functionalized metal organic frameworks sorbents
Shi F, et al
Applied Catalysis. B, Environmental, 103(3-4), 261-265 (2011)
Microwave-promoted aminocarbonylations of aryl chlorides using Mo(CO)(6) as a solid carbon monoxide source.
Olof Lagerlund et al.
Journal of combinatorial chemistry, 8(1), 4-6 (2006-01-10)
Patrik Nordeman et al.
The Journal of organic chemistry, 77(24), 11393-11398 (2012-12-05)
A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the

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