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蒸汽密度
9.1 (vs air)
检测方案
98%
形式
solid
反应适用性
core: molybdenum
reagent type: catalyst
bp
156 °C (lit.)
mp
150 °C (dec.) (lit.)
密度
1.96 g/mL at 25 °C (lit.)
SMILES字符串
[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/6CO.Mo/c6*1-2;
InChI key
KMKBZNSIJQWHJA-UHFFFAOYSA-N
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一般描述
六羰基钼是一种白色结晶固体，在 150 ° C 下熔融，密度为 1.96 gm/cc，不溶于水和可溶在大多数有机溶剂中。
应用
用于二氧化硅的接枝，作为烯烃环氧化的催化剂， 从液体燃料中吸附有机硫化合物，作为生产有机钼染料和热分解镀钼的前体。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Selective adsorption of dibenzothiophene by functionalized metal organic frameworks sorbents
Shi F, et al
Applied Catalysis. B, Environmental, 103(3-4), 261-265 (2011)
Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor
Abrantes M, et al
Catalysis Communications, 15(1), 64-67 (2011)
Advanced Synthesis & Catalysis, 352(10), 1759-1769 (2010)
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
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