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Merck
CN

199958

六羰基钼

98%

别名:

羰化钼

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线性分子式:
Mo(CO)6
化学文摘社编号:
分子量:
264.00
UNSPSC Code:
12352103
PubChem Substance ID:
EC Number:
237-713-3
MDL number:
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产品名称

六羰基钼, 98%

InChI key

KMKBZNSIJQWHJA-UHFFFAOYSA-N

InChI

1S/6CO.Mo/c6*1-2;

SMILES string

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

vapor density

9.1 (vs air)

assay

98%

form

solid

reaction suitability

core: molybdenum
reagent type: catalyst

bp

156 °C (lit.)

mp

150 °C (dec.) (lit.)

density

1.96 g/mL at 25 °C (lit.)

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Application

用于二氧化硅的接枝,作为烯烃环氧化的催化剂, 从液体燃料中吸附有机硫化合物,作为生产有机钼染料和热分解镀钼的前体。

General description

六羰基钼是一种白色结晶固体,在 150 ° C 下熔融,密度为 1.96 gm/cc,不溶于水和可溶在大多数有机溶剂中。

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Inhalation

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Selective adsorption of dibenzothiophene by functionalized metal organic frameworks sorbents
Shi F, et al
Applied Catalysis. B, Environmental, 103(3-4), 261-265 (2011)
Advanced Synthesis & Catalysis, 352(10), 1759-1769 (2010)
Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor
Abrantes M, et al
Catalysis Communications, 15(1), 64-67 (2011)
In situ generation of carbon monoxide from solid molybdenum hexacarbonyl. A convenient and fast route to palladium-catalyzed carbonylation reactions.
Nils-Fredrik K Kaiser et al.
Journal of combinatorial chemistry, 4(2), 109-111 (2002-03-12)
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in

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