形式
liquid
质量水平
浓度
2.0 M in toluene
密度
0.81 g/mL at 25 °C
SMILES字符串
C[Al](C)C
InChI
1S/3CH3.Al/h3*1H3;
InChI key
JLTRXTDYQLMHGR-UHFFFAOYSA-N
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应用
三甲基铝溶液可用作合成以下物质的试剂:
- 通过不饱和糖苷的立体选择性重排生成多羟基化环己烷
- 用于烯烃聚合的部分水解三甲基铝(PHT)催化剂
- 采用镍-1,3-二环己基咪唑2-亚基催化体系通过苯甲醚衍生物的甲基化作用生成甲苯
用于最近报道的基于Oppenauer 反应的Al催化氧化,得到了高产量的醛和酮。 作为联萘酚的 (1:1) 络合物,以Novozym 435催化仲醇的动态动力学拆分。
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Danger
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1
靶器官
Central nervous system
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
39.2 °F - closed cup
闪点(°C)
4 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Partially hydrolyzed trimethylaluminum (PHT) as heterogeneous cocatalyst for the polymerization of olefins with metallocene complexes
Journal of Applied Polymer Science, 80(3), 454-466 (2001)
Nickel-catalyzed cross-coupling of anisole derivatives with trimethylaluminum through the cleavage of carbon-oxygen bonds
Chemistry Letters (Jpn), 44(12), 1729-1731 (2015)
Trimethylaluminium promoted rearrangements of unsaturated sugars into cyclohexanes
Tetrahedron Asymmetry, 15(4), 699-703 (2004)
Journal of the American Chemical Society, 128(39), 12596-12597 (2006-09-28)
A highly active and selective Al-based catalytic Oppenauer (O) oxidation is reported. Quantitative and selective oxidations of a variety of benzylic, propargylic, allylic, and aliphatic primary and secondary alcohols were achieved using nitrobenzaldehyde derivatives as the oxidant and simple aluminum
Lipase/aluminum-catalyzed dynamic kinetic resolution of secondary alcohols.
Angewandte Chemie (International ed. in English), 45(39), 6567-6570 (2006-09-05)
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